22768-01-0

Basic information

• Product Name: benzyl prop-2-en-1-yl carbonate
• CAS NO: 22768-01-0
• Molecular Formula: C₁₁H₁₂O₃
• Molecular Weight: 192.2112
• Mol File: 22768-01-0.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 262.6°C at 760 mmHg
• Flash Point: 98.6°C
• Density: 1.087g/cm³
• Vapor Pressure: 0.0108mmHg at 25°C
• Refractive Index: 1.511
• CAS DataBase Reference: benzyl prop-2-en-1-yl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl prop-2-en-1-yl carbonate(22768-01-0)
• EPA Substance Registry System: benzyl prop-2-en-1-yl carbonate(22768-01-0)

Safety Data

• Hazardous Substances Data: 22768-01-0(Hazardous Substances Data)

Usage

General Description

Benzyl prop-2-en-1-yl carbonate is a chemical compound that is used in the production of various products including fragrances, cosmetics, and pharmaceuticals. It is commonly used as a fragrance ingredient due to its sweet and floral odor. Additionally, it has applications in the synthesis of organic compounds and is used as a building block in the production of polymers and plastics. Benzyl prop-2-en-1-yl carbonate has a prop-2-en-1-yl group attached to the benzyl group, and the carbonate functional group which gives it its unique properties and versatility in various industrial and commercial applications.

Upstream product

• 2937-50-0 Allyl chloroformate 
• 100-51-6 benzyl alcohol 
• 83395-39-5 2-propen-1-yl 1H-imidazole-1-carboxylate 
• 100-39-0 benzyl bromide 
• 107-18-6 allyl alcohol 
• 106-95-6 allyl bromide 
• 124-38-9 carbon dioxide 
• 61296-25-1 N,N-Dimethylformamide diallyl acetal 
• 2016-04-8 N,N-dimethylformamide dibenzyl acetal 

Downstream Products

• 14593-43-2 benzyl allyl ether 
• 100-52-7 benzaldehyde 
• 187737-37-7 propene 
• 100-51-6 benzyl alcohol 
• 198422-64-9 (1S,2S)-N-(2-hydroxycyclohexyl)carbamate 
• 134108-76-2 (1R,2R)-2-hydroxycyclohexylcarbamic acid benzyl ester 
• 28627-36-3 5,5-dimethyl-2,2-diallylcyclohexane-1,3-dione 
• 77118-87-7 (S)-1-Phenyl-3-buten-1-ol 
• 25919-06-6 benzyl n-propyl carbonate 

Relevant articles and documents

Carbon Dioxide Utilisation for the Synthesis of Unsymmetrical Dialkyl and Cyclic Carbonates Promoted by Basic Ionic Liquids

An efficient and greener synthesis of unsymmetrical organic carbonates mediated by Hünig's base-appended basic ionic liquids, via carbon dioxide conversion, is described here. These ionic liquids were found to be effective bases for the fixation of carbon dioxide by various alcohols and benzyl bromide, at room temperature. When the alcohol and the halide functionalities are present within the same substrate, the reaction cleanly produces a cyclic carbonate. These functionalised basic ionic liquids were fully recyclable with no loss product yields.

Method for producing symmetrical and asymmetrical carbonates

Process for the preparation of symmetrical and asymmetrical carbonates of the general formula I by reaction of alcohols of the general formula II and alkyl or aryl halides of the general formula III,R—OH??IIR′—HAL??IIIwith carbon dioxide and caesium carbonate at room temperature in dipolar aprotic solvents.

A New Simple One-Pot Regioselective Preparation of Mixed Diesters of Carbonic Acid

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