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1-Allylimidazole is a clear colorless to light yellow liquid that serves as an important raw material and intermediate in various industries, including organic synthesis, pharmaceuticals, agrochemicals, and dyestuff.

31410-01-2

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31410-01-2 Usage

Uses

Used in Organic Synthesis:
1-Allylimidazole is used as a crucial intermediate for the development of new organic compounds, contributing to the advancement of chemical research and innovation.
Used in Pharmaceuticals:
1-Allylimidazole is utilized as a key component in the synthesis of various pharmaceutical products, playing a significant role in the development of new medications and therapies.
Used in Agrochemicals:
1-Allylimidazole is employed as a vital raw material in the production of agrochemicals, such as pesticides and fertilizers, to enhance agricultural productivity and crop protection.
Used in Dyestuff:
1-Allylimidazole is used as an essential intermediate in the manufacturing of dyes and pigments, contributing to the vibrant colors and hues in various industries, including textiles, plastics, and printing.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 1319, 1994 DOI: 10.1021/jo00085a020

Check Digit Verification of cas no

The CAS Registry Mumber 31410-01-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,1,4,1 and 0 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 31410-01:
(7*3)+(6*1)+(5*4)+(4*1)+(3*0)+(2*0)+(1*1)=52
52 % 10 = 2
So 31410-01-2 is a valid CAS Registry Number.
InChI:InChI=1/C6H8N2/c1-2-4-8-5-3-7-6-8/h2-3,5-6H,1,4H2

31410-01-2 Well-known Company Product Price

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  • Detail
  • Alfa Aesar

  • (L11053)  1-Allylimidazole, 99%   

  • 31410-01-2

  • 10g

  • 165.0CNY

  • Detail
  • Alfa Aesar

  • (L11053)  1-Allylimidazole, 99%   

  • 31410-01-2

  • 50g

  • 698.0CNY

  • Detail

31410-01-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-prop-2-enylimidazole

1.2 Other means of identification

Product number -
Other names 1-(prop-2-enyl)-1H-imidazole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:31410-01-2 SDS

31410-01-2Synthetic route

1H-imidazole
288-32-4

1H-imidazole

vinyl benzoate
583-04-0

vinyl benzoate

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
With briphos; bis(dibenzylideneacetone)-palladium(0) In dichloromethane at 30℃; for 12h;99%
1H-imidazole
288-32-4

1H-imidazole

allyl alcohol
107-18-6

allyl alcohol

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
With 2,3,4,5,6-pentafluorophenol; briphos; bis(dibenzylideneacetone)-palladium(0) In dichloromethane at 30℃; for 6h; Kinetics; Concentration; Solvent; Reagent/catalyst; Inert atmosphere;96%
1H-imidazole
288-32-4

1H-imidazole

allyl bromide
106-95-6

allyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
With potassium hydroxide; PEG-400-Et2 In water; benzene at 30℃; for 2h;93%
Stage #1: 1H-imidazole With sodium hydride In tetrahydrofuran for 1h; Heating;
Stage #2: allyl bromide In tetrahydrofuran at 50℃; for 3h; Further stages.;
32%
With tetra-(n-butyl)ammonium iodide; sodium hydroxide In toluene
formaldehyd
50-00-0

formaldehyd

Glyoxal
131543-46-9

Glyoxal

ammonia
7664-41-7

ammonia

1-amino-2-propene
107-11-9

1-amino-2-propene

A

1H-imidazole
288-32-4

1H-imidazole

B

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
Stage #1: formaldehyd; ammonia; 1-amino-2-propene In water at 25℃; for 1h;
Stage #2: Glyoxal; ammonia at 25℃; for 1h;
A 4%
B 93%
allyl bromide
106-95-6

allyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
76%
1H-imidazole
288-32-4

1H-imidazole

allyl bromide
106-95-6

allyl bromide

A

1-allylimidazole
31410-01-2

1-allylimidazole

B

(Z)-1-(1-propenyl)imidazole

(Z)-1-(1-propenyl)imidazole

C

(E)-1-(prop-1-en-1-yl)-1H-imidazole

(E)-1-(prop-1-en-1-yl)-1H-imidazole

Conditions
ConditionsYield
With potassium tert-butylate; tetrabutylammomium bromide at 0℃; for 5h;A 37%
B n/a
C n/a
With potassium tert-butylate; tetrabutylammomium bromide at 0℃; for 5h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
3-Acetyl-1-allyl-3H-imidazol-1-ium; bromide

3-Acetyl-1-allyl-3H-imidazol-1-ium; bromide

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
With sodium carbonate In water Yield given;
1-(2-cyanoethyl)-3-allyllimidazolium bromide

1-(2-cyanoethyl)-3-allyllimidazolium bromide

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
With sodium hydroxide for 0.833333h; Ambient temperature; Yield given;
1H-imidazole
288-32-4

1H-imidazole

3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
In water
1H-imidazole
288-32-4

1H-imidazole

2-propen-1-yl 1H-imidazole-1-carboxylate
83395-39-5

2-propen-1-yl 1H-imidazole-1-carboxylate

1-allylimidazole
31410-01-2

1-allylimidazole

Conditions
ConditionsYield
In [D3]acetonitrile at 80℃; for 16h; Inert atmosphere; Sealed vial;
trimethoxonium tetrafluoroborate
420-37-1

trimethoxonium tetrafluoroborate

1-allylimidazole
31410-01-2

1-allylimidazole

1-methyl-3-(prop-2-enyl)-1H-imidazol-3-ium tetrafluoroborate

1-methyl-3-(prop-2-enyl)-1H-imidazol-3-ium tetrafluoroborate

Conditions
ConditionsYield
In hexane at -78 - 20℃;100%
1-allylimidazole
31410-01-2

1-allylimidazole

(E)-1-(prop-1-en-1-yl)-1H-imidazole

(E)-1-(prop-1-en-1-yl)-1H-imidazole

Conditions
ConditionsYield
With 18-crown-6 ether; potassium hydroxide In benzene-d6 at 20℃; for 24h; Inert atmosphere;100%
2-(bromomethyl)pyridine hydrobromide
31106-82-8

2-(bromomethyl)pyridine hydrobromide

1-allylimidazole
31410-01-2

1-allylimidazole

1-allyl-3-((2-pyridyl)methyl)imidazolium bromide
1589521-61-8

1-allyl-3-((2-pyridyl)methyl)imidazolium bromide

Conditions
ConditionsYield
With potassium carbonate In acetonitrile at 20℃; for 24h;100%
With potassium carbonate In acetonitrile at 60℃; for 18h;100%
With potassium carbonate In acetonitrile at 60℃; for 18h;100%
allyl bromide
106-95-6

allyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

1,3-bis(2-propenyl)imidazolium bromide

1,3-bis(2-propenyl)imidazolium bromide

Conditions
ConditionsYield
In acetonitrile at 100℃; for 24h; Inert atmosphere;99%
In methanol at 20℃; for 120h;95%
at 60℃; for 24h; Inert atmosphere;88%
In toluene at 20℃;
at 65℃; for 12h;
tributyl borane
122-56-5

tributyl borane

1-allylimidazole
31410-01-2

1-allylimidazole

N-allyl-imidazole-tributylborane
868628-72-2

N-allyl-imidazole-tributylborane

Conditions
ConditionsYield
In tetrahydrofuran inert atm., equimol. at room temp. for 12 h;99%
propargyl bromide
106-96-7

propargyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

3-allyl-1-prop-2-ynyl-3H-imidazol-1-ium; bromide

3-allyl-1-prop-2-ynyl-3H-imidazol-1-ium; bromide

Conditions
ConditionsYield
In dichloromethane; toluene at 20℃;98%
at 65℃; for 12h;
1-allylimidazole
31410-01-2

1-allylimidazole

trimethyl orthoformate
149-73-5

trimethyl orthoformate

1-allyl-3-methylimidazolium hexafluorophosphate

1-allyl-3-methylimidazolium hexafluorophosphate

Conditions
ConditionsYield
With ammonium hexafluorophosphate Schlenk technique; Reflux;98%
With ammonium hexafluorophosphate at 110℃; for 22h; Inert atmosphere;97%
1-allylimidazole
31410-01-2

1-allylimidazole

trimethyl orthoformate
149-73-5

trimethyl orthoformate

1-methyl-3-(prop-2-enyl)-1H-imidazol-3-ium tetrafluoroborate

1-methyl-3-(prop-2-enyl)-1H-imidazol-3-ium tetrafluoroborate

Conditions
ConditionsYield
With ammonium tetrafluoroborate at 110℃; for 22h; Inert atmosphere;96%
4,4'-bis(chloromethyl)biphenyl
1667-10-3

4,4'-bis(chloromethyl)biphenyl

1-allylimidazole
31410-01-2

1-allylimidazole

C26H28N4(2+)*2Cl(1-)

C26H28N4(2+)*2Cl(1-)

Conditions
ConditionsYield
In acetonitrile at 90℃; for 16h; Inert atmosphere;95%
mono-6-deoxy-6-(p-tolylsulphonyl)-β-cyclodextrin
67217-55-4

mono-6-deoxy-6-(p-tolylsulphonyl)-β-cyclodextrin

1-allylimidazole
31410-01-2

1-allylimidazole

mono-6A-deoxy-6-(1-allylimidazolium)-β-cyclodextrin tosylate

mono-6A-deoxy-6-(1-allylimidazolium)-β-cyclodextrin tosylate

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 85℃; for 12h; Inert atmosphere;94%
In N,N-dimethyl-formamide at 85℃;
1,10-dibromodecane
4101-68-2

1,10-dibromodecane

1-allylimidazole
31410-01-2

1-allylimidazole

3,3'-(1,10-decadiyl)bis-1,1'-allylimidazolium bromide

3,3'-(1,10-decadiyl)bis-1,1'-allylimidazolium bromide

Conditions
ConditionsYield
at 70℃; Inert atmosphere;94%
1-allylimidazole
31410-01-2

1-allylimidazole

(bromomethyl)pentafluorobenzene
1765-40-8

(bromomethyl)pentafluorobenzene

3-allyl-1-(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide

3-allyl-1-(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide

Conditions
ConditionsYield
In acetonitrile for 48h; Inert atmosphere; Reflux;93%
propyl bromide
106-94-5

propyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

1-allyl-3-propylimidazolium bromide

1-allyl-3-propylimidazolium bromide

Conditions
ConditionsYield
at 70℃; for 48h; Inert atmosphere;92%
In toluene at 20℃;
sodium tetrahydroborate
16940-66-2

sodium tetrahydroborate

1-allylimidazole
31410-01-2

1-allylimidazole

C6H11BN2

C6H11BN2

Conditions
ConditionsYield
With ammonium sulfate In tetrahydrofuran at 20℃; for 8h; Reflux;92%
(2Z)-4-bromo-1,3-diphenylbut-2-en-1-one
7462-71-7, 15295-67-7, 59310-37-1

(2Z)-4-bromo-1,3-diphenylbut-2-en-1-one

1-allylimidazole
31410-01-2

1-allylimidazole

Br(1-)*C22H21N2O(1+)
1242247-32-0

Br(1-)*C22H21N2O(1+)

Conditions
ConditionsYield
In benzene at 20℃;91%
1-allylimidazole
31410-01-2

1-allylimidazole

benzene
71-43-2

benzene

1-(2-phenylpropyl)-1H-imidazole

1-(2-phenylpropyl)-1H-imidazole

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 50℃; for 3h;90%
ethyl bromide
74-96-4

ethyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

1-ethyl,3-allyl-imidazolium bromide
652134-09-3

1-ethyl,3-allyl-imidazolium bromide

Conditions
ConditionsYield
at 70℃; for 30h; Inert atmosphere;90%
In toluene at 20℃;
1-Bromopentane
110-53-2

1-Bromopentane

1-allylimidazole
31410-01-2

1-allylimidazole

1-pentyl-3-allylimidazolium bromide

1-pentyl-3-allylimidazolium bromide

Conditions
ConditionsYield
at 0 - 25℃; for 24h;90%
In toluene at 20℃;
1-bromo-octane
111-83-1

1-bromo-octane

1-allylimidazole
31410-01-2

1-allylimidazole

1-propenyl-3-octylimidazolium bromide

1-propenyl-3-octylimidazolium bromide

Conditions
ConditionsYield
at 0 - 25℃; for 24h;89%
In toluene at 20℃;
In acetonitrile at 55℃; for 24h;
trimethylamine borane
98161-63-8

trimethylamine borane

iodine
7553-56-2

iodine

1-allylimidazole
31410-01-2

1-allylimidazole

(1-allyl-1H-imidazole-3-yl)-(trimethylamine)dihydroboronium iodide

(1-allyl-1H-imidazole-3-yl)-(trimethylamine)dihydroboronium iodide

Conditions
ConditionsYield
In toluene88%
1-allylimidazole
31410-01-2

1-allylimidazole

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

1-(2-propenyl)-3-methylimidazolium-2-carboxylate
1308849-58-2

1-(2-propenyl)-3-methylimidazolium-2-carboxylate

Conditions
ConditionsYield
at 80 - 90℃; Neat (no solvent);87%
2-cyano-1-phenylacetylene
935-02-4

2-cyano-1-phenylacetylene

1-allylimidazole
31410-01-2

1-allylimidazole

(Z)-3-(3-allyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl)-3-phenyl-2-propenenitrile
1541206-67-0

(Z)-3-(3-allyl-2-thioxo-2,3-dihydro-1H-imidazol-1-yl)-3-phenyl-2-propenenitrile

Conditions
ConditionsYield
With sulfur In neat (no solvent) at 20 - 25℃; for 24h; stereoselective reaction;87%
2,3,4,5,6,-pentamethylbenzyl bromide
53442-65-2

2,3,4,5,6,-pentamethylbenzyl bromide

1-allylimidazole
31410-01-2

1-allylimidazole

C18H25N2(1+)*Br(1-)

C18H25N2(1+)*Br(1-)

Conditions
ConditionsYield
In toluene at 20℃; for 3h; Inert atmosphere; Schlenk technique;87%
triethylamine borane
88746-20-7

triethylamine borane

iodine
7553-56-2

iodine

1-allylimidazole
31410-01-2

1-allylimidazole

(1-allyl-1H-imidazole-3-yl)-(triethylamine)dihydroboronium iodide

(1-allyl-1H-imidazole-3-yl)-(triethylamine)dihydroboronium iodide

Conditions
ConditionsYield
Stage #1: triethylamine borane; iodine In toluene at 20℃; for 4.5h; Cooling with ice;
Stage #2: 1-allylimidazole In toluene at 20℃; for 2h;
87%
zinc diacetate
557-34-6

zinc diacetate

1-allylimidazole
31410-01-2

1-allylimidazole

bis(N-allylimidazole)zinc diacetate

bis(N-allylimidazole)zinc diacetate

Conditions
ConditionsYield
In diethyl ether; acetone at 20℃; for 12h;87%

31410-01-2Relevant articles and documents

On the effects of head-group volume on the adsorption and aggregation of 1-(n-hexadecyl)-3-Cm-imidazolium bromide and chloride surfactants in aqueous solutions

Keppeler, Nicolas,Galgano, Paula D.,da Silva Santos, Soraya,Malek, Naved I.,El Seoud, Omar A.

, (2021/02/09)

The effects of the length of alkyl side chain (Cm) of ionic liquid-based surfactants (ILBSs) on their adsorption at the water/air interface, and aggregation in aqueous solutions were investigated for the series 1-(n-hexadecyl)-3-Cm-imidazolium bromides and chlorides, where Cm = C1-C4 for the bromides, and C1-C5 for the chlorides. These physicochemical properties were calculated from surface tension, conductivity, and fluorescence data. It was found that increasing the length of Cm (i.e., volume of the head group) leads to enhancement of surface activity, increase in the area per surfactant molecule at the water/air interface (Amin) and the degree of counter-ion dissociation (αmic). Our data also indicated that increasing the volume of the head group results in a decrease of the critical micelle concentration (cmc), Gibb's free energy of adsorption and micellization, and microscopic polarity of interfacial water. In order to delineate the effects of the presence of unsaturation in the HG, we included members that carry Cm = vinyl and allyl in the bromide series. The effect of these groups was found to be similar to removing a methylene group from Cm. The dependence of the solubilization of a lipophilic dye (Sudan IV) and a drug (nitrendipine) on the length of Cm was also studied.

Synthesis, crystal analysis and DFT calculations of Ni(II) and Pd(II) complexes of 3,3'-((1,2-phenylenebis(azanediyl))bis(2-oxoethane-2,1-diyl))bis(1-allyl-1H-imidazole-3-ium)

Al-Azmi, Amal

, p. 179 - 187 (2018/12/11)

Ni(II) and Pd(II) Complexes of 3,3'-((1,2-phenylenebis(azanediyl))bis(2-oxoethane-2,1-diyl))bis(1-allyl-1H-imidazole-3-ium) were synthesised in good yield and characterized by spectroscopic and X-ray diffraction techniques. These novel complexes, which are neutral in charge, possess square planar geometry where the coordination of the tetradentate ligand is through C2 of the imidazole moiety. These complexes are identified to be single cis-isomers as confirmed by 1H NMR and single crystal X-ray diffraction data. DFT/B3LYP calculations were also conducted using the theoretical model of the precursor heterocyclic ligand and Ni(II) and Pd(II) metal complexes. The results of these theoretical data which are calculated to be the structural parameters of optimized structures exhibited good agreement with those obtained from X-ray crystal diffraction analysis. Both metal complexes are subjected to further theoretical studies such as determination of the HOMO-LUMO gap, molecular electrostatic potential (MEP) and calculation of reactivity descriptors and the obtained results attest the superiority of these compounds as novel heterocyclic functional materials.

Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive

Kang, Kyungjun,Kim, Jaewook,Lee, Ansoo,Kim, Woo Youn,Kim, Hyunwoo

supporting information, p. 616 - 619 (2016/02/18)

A mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite (briphos) ligand together with Pd(dba)2 is a highly efficient catalyst, and an acid additive involved in the rate-determining step promotes the catalytic cycle. The coupling reaction of allylic alcohols with N-heterocycles including imidazoles, benzimidazoles, and triazole proceeds under mild reaction conditions with high yields using Pd/briphos and pentafluorophenol.

Synthesis, Characterization, Crystal Structures, and Catalytic C-C Coupling and Hydrosilylation Reactions of Palladium(II) Complexes Derived from CNC Pincer-Type N-Heterocyclic Carbenes

Haque, Rosenani A.,Asekunowo, Patrick O.,Budagumpi, Srinivasa,Shao, Linjun

, p. 3169 - 3181 (2015/07/15)

A series of pyridine linker containing bis(benz)imidazolium salts serving as precursors to CNC pincer-type N-heterocyclic carbene (NHC) ligands were prepared by successive N-alkylation of the azole core. Binuclear NHC complexes of silver(I) were synthesized by in situ deprotonation of the corresponding (benz)imidazolium salt with silver(I) oxide in acetonitrile at elevated temperature in the dark. Subsequently, pincer-type palladium(II)-NHC complexes were prepared by transmetalation using silver(I)-NHC complexes in acetonitrile at elevated temperatures. All compounds were fully characterized by elemental analysis, FTIR spectroscopy, and 1H and 13C NMR spectroscopy. X-ray diffraction studies on single crystals of three compounds confirmed the distorted square-planar geometry around the palladium(II) center. All complexes are monomeric in nature, and the bis-NHC ligand chelates in the CNC mode. The effective catalytic potentials of the palladium complexes were demonstrated by their high activities in aqueous-phase Suzuki-Miyaura and Heck-Mizoroki cross-coupling reactions of phenylboronic acid and n-butyl acrylate with a range of functionalized bromobenzene derivatives. The former coupling reaction afforded biphenyls in yields of 71-99%, whereas the latter reaction evidenced low yields of the n-butyl cinnamates. Further, all the palladium complexes were studied for their potential in a catalytic hydrosilylation reaction.

Design, synthesis, antiviral, and cytostatic evaluation of novel isoxazolidine analogs of homonucleotides

Lysakowska, Magdalena,Balzarini, Jan,Piotrowska, Dorota G.

, p. 341 - 353 (2014/05/20)

Moderate diastereoselectivities (d.e. 2-62%) of isoxazolidine homonucleotides were observed for cycloadditions between N-methyl-C- (diethoxyphosphoryl)nitrone and N-allyl nucleobases, with trans-isoxazolidines predominating. The stereochemistry of the substituted isoxazolidines was established based on 2D NOE experiments performed for uracil-containing cycloadducts. The cis- and trans-isoxazolidine phosphonates obtained herein were evaluated in vitro for activity against a broad range of DNA and RNA viruses. None of the compounds were endowed with antiviral activity at subtoxic concentrations, but some of them were found to inhibit the proliferation of L1210 cells with IC50 values in the range of 33-100 μM.

On the reactivity of imidazole carbamates and ureas and their use as esterification and amidation reagents

Heller, Stephen T.,Sarpong, Richmond

experimental part, p. 8851 - 8859 (2011/12/02)

The optimization, substrate scope, and mechanism of esterification and amidation of carboxylic acids mediated by imidazole-based reagents are discussed. The innate reactivity of carbonylimidazole reagents with a range of nucleophiles is also explored. New reagents developed for the synthesis of α,β-unsaturated esters are described, as are reagents for the preparation of tertiary amides directly from carboxylic acids.

METHOD OF PREPARING DIALKYLCARBONATES

-

Page/Page column 11; 12, (2008/06/13)

The present invention relates to a process of preparing dialkylcarbonates, and particularly to an improved process of preparing dialkylcarbonates, which comprises performing a reaction between an alcohol compound and a chloroformate derivative in the presence of an imidazole compound, thereby enabling to prepare dialkylcarbonates with high yield in a mild condition without using toxic raw materials and to easily separate impurities.

METHOD OF PREPARING FLUORINATED ALKOXYTRIALKYLSILANES

-

Page/Page column 11-12, (2008/06/13)

The present invention relates to a process for preparing alkoxytrialkylsilane, and in particular to a process, wherein an imidazole compound is added as a HCl scavenger and a reaction promoter, thereby enhancing the yield of fluorinated alkoxytrialkylsilanes and reducing corrosion problem.

MANUFACTURING METHOD OF 1-SUBSTITUTED IMIDAZOLE COMPOUND

-

Page 5, (2010/02/11)

PROBLEM TO BE SOLVED: To provide a high-yield manufacturing method of a 1-substituted imidazole compound which is expected to be useful as a curing agent for epoxy resins, polyurethane resins or the like, as an intermediate of various agrochemicals, antibiotics or pharmaceuticals such as anti-AIDS agents or the like, or as dye intermediates. SOLUTION: An aldehyde compound is reacted with a primary amine to give an imine compound, and subsequently an α,β-dicarbonyl compound and ammonia are added and allowed to react with the imine compound. Preferably, the α,β-dicarbonyl compound and ammonia are simultaneously added.

Tin-free radical sequences under acidic conditions. Convergent access to azole-containing structures

Gagosz, Fabien,Zard, Samir Z.

, p. 4345 - 4348 (2007/10/03)

(equation presented) Various xanthates add efficiently to olefins bearing [1,2,4]triazole, imidazole, or benzimidazole moieties in the presence of camphorsulfonic acid via a radical chain reaction initiated by a small amount of lauroyl peroxide. The adducts may be transformed to more complex molecules by implementing a further radical cyclization.

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