83670-13-7

Upstream product

• 104785-55-9 2,4-dimethylquinoline 3-carboxylic acid 
• 104785-56-0 11R-3-(N-α-methylbenzyl)carbamoyl-2,4-dimethylquinoline 
• 104785-54-8 2,4-dimethylquinoline-3-carboxylic acid ethyl ester 
• 551-93-9 2-aminoacetophenone 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 

Downstream Products

• 104465-70-5 (4R)-3--1,2,4-trimethyl-1,4-dihydroquinoline 
• 100-51-6 benzyl alcohol 

Relevant academic research and scientific papers

NAD(P)+-NAD(P)H MODELS. 57. STEROCHEMISTRY IN (NET) HYDRIDE TRANSFER FROM AND TO NAD(P)+-NAD(P)H MODELS: CHIRALITY SINK

NAD(P)H/NAD(P)+ and related compounds have intrinsic chirality against the axis along the C3-Ccarbonyl single bond.A model compound which has a stable conformation with respect to this chirality was synthesized and the conformational relationship between the carbonyl dipole and the reacting hydrogen was studied.It has been concluded that there is a relationship between conformations of these groups both in reduction and in oxidation provided the substrate is a neutral species.The result is discussed in relation with the hypothesis proposed previously on the basis of quantum chemical calculations.