837-64-9

Basic information

• Product Name: 2,4-DINITRO-N,N-DIETHYLANILINE
• Synonyms: 2,4-DINITRO-N,N-DIETHYLANILINE;N1,N1-DIETHYL-2,4-DINITROANILINE;(2,4-dinitrophenyl)-diethyl-amine
• CAS NO: 837-64-9
• Molecular Formula: C₁₀H₁₃N₃O₄
• Molecular Weight: 239.23
• Mol File: 837-64-9.mol
• Article Data: 17

Chemical Properties

• Boiling Point: 371.1°C at 760 mmHg
• Flash Point: 178.3°C
• Appearance: /
• Density: 1.299g/cm³
• Vapor Pressure: 1.05E-05mmHg at 25°C
• Refractive Index: 1.599
• CAS DataBase Reference: 2,4-DINITRO-N,N-DIETHYLANILINE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-DINITRO-N,N-DIETHYLANILINE(837-64-9)
• EPA Substance Registry System: 2,4-DINITRO-N,N-DIETHYLANILINE(837-64-9)

Safety Data

• Hazardous Substances Data: 837-64-9(Hazardous Substances Data)

Usage

General Description

2,4-Dinitro-N,N-diethylaniline is a yellow to orange crystalline solid that is primarily used as a dye intermediate and as a corrosion inhibitor in the oil and gas industry. It is also used as a starting material in the synthesis of various organic compounds. However, it is considered toxic and potentially harmful to human health. Exposure to this chemical can cause irritation to the skin, eyes, and respiratory system, and it may also cause adverse effects on the liver and kidneys. Additionally, it is classified as a possible human carcinogen. Therefore, proper precautions should be taken when handling or working with 2,4-dinitro-N,N-diethylaniline to minimize exposure and potential health risks.

InChI:InChI=1/C10H13N3O4/c1-3-11(4-2)9-6-5-8(12(14)15)7-10(9)13(16)17/h5-7H,3-4H2,1-2H3

Upstream product

• 109-89-7 diethylamine 
• 97-00-7 1-chloro-2,4-dinitro-benzene 
• 121-44-8 triethylamine 
• 5351-04-2 3-diethylaminopropionitrile 
• 7664-93-9 sulfuric acid 
• 7697-37-2 nitric acid 
• 91-66-7 N,N-diethylaniline 
• 64-19-7 acetic acid 
• 3588-91-8 4,4'-Bis-diaethylamino-azobenzol 
• 89-02-1 2,4-dinitrobenzenesulfonic acid 
• 772-54-3 N,N-diethylbenzylamine 
• 70-34-8 2,4-Dinitrofluorobenzene 
• 709-49-9 1-iodo-2,4-dinitrobenzene 
• 617-84-5 N-formyldiethylamine 

Downstream Products

• 3846-50-2 2,4-dinitro-N-ethylaniline 
• 46161-15-3 N¹,N¹,diethyl-benzene-1,2,4-triyltriamine 
• 857596-68-0 N-ethyl-2,4-dinitro-N-nitroso-aniline 
• 109-89-7 diethylamine 
• 97-02-9 2,4-Dinitroanilin 
• 51-28-5 2,4-Dinitrophenol 

Relevant articles and documents

Photoredox catalyzed dealkylative aromatic halogen substitution with tertiary amines

A reaction of aromatic halides bearing electron-withdrawing groups with tertiary amines in the presence of an iridium catalyst under blue light irradiation is described. Products of the aromatic substitution of the halide by the dialkylamino fragment are

Synthesis of o-Nitroarylamines via Ipso Nucleophilic Substitution of Sulfonic Acids

A mild, efficient, and eco-friendly method for the synthesis of o-nitroarylamine from o-nitroaryl sulfonic acid via ipso nucleophilic aryl substitution by amine is described. The products have been obtained with good yields at room temperature without the assistance of any metal, activating agent, or toxic oxidant. This method is useful for racemization-free synthesis of N-aryl amino acid esters.

Mechanistic assessment of SNAr displacement of halides from 1-Halo-2,4-dinitrobenzenes by selected primary and secondary amines: Br?nsted and Mayr analyses

Pseudo-first-order rate constants (kobsd) have been measured spectrophotometrically for nucleophilic substitution reactions of 1-X-2,4-dinitrobenzenes (1a-d, X = F, Cl, Br, I) with various primary and secondary amines in MeCN and H2O