83852-28-2

Upstream product

• 501-53-1 benzyl chloroformate 
• 1161-13-3 N-Cbz-L-Phe 
• 109-76-2 Trimethylenediamine 
• 63-91-2 L-phenylalanine 
• 3401-36-3 (N-benzyloxycarbonyl)-L-alanine N-hydroxysuccinimide ester 
• 3397-32-8 N-(benzyloxycarbonyl)-phenylalanine-N-hydroxysuccinimide ester 

Downstream Products

• 1025009-10-2 C₅₆H₆₄N₈O₄ 
• 119274-66-7 (3S,9S)-3,9-dibenzyl-1,4,8,11-tetraazacyclotetradecane-5,7-dione 
• 94405-01-3 (2S,10S)-1,11-diphenyl-4,8-diazaundecane-2,10-diamine 
• 83852-29-3 (S,S)-N,N'-bis(phenylalanyl)-1,3-diaminopropane 

Relevant academic research and scientific papers

Copper(ii) complexes of macrocyclic and open-chain pseudopeptidic ligands: synthesis, characterization and interaction with dicarboxylates

Mono- and dinuclear Cu(ii) complexes were prepared with pseudopeptidic open chain and macrocyclic ligands, respectively. They were characterized by UV-vis spectroscopy, EPR, HRMS and X-ray diffraction. The Cu(ii) cation is coordinated by two amines and tw

Cu2+ recognition by N,N′-benzylated bis(amino amides)

Two new C2-symmetric N,N′-benzylated bis(amino amides) have been synthesised and their interaction with different transition metals studied using a variety of techniques including UV-Vis and CD spectroscopy or ESI-MS. The determination of the c

A configuration can control the synthesis of 2 - (4 - nitro) butyryl pyridine nitrogen - oxidation method of the (by machine translation)

The invention relates to a configuration can control the synthesis of 2 - (4 - nitro) butyryl pyridine nitrogen - oxygen compounds of the method, comprises the following steps: 1) will be 2 - ene acyl pyridine nitrogen - arrive compound and nitromethane o

A simple peptidomimetic that self-associates on the solid state to form a nanoporous architecture containing chiral π-channels

The crystal structure of a simple peptidomimetic compound, derived from phenylalanine, shows the formation of a nanoporous architecture containing monodimensional π-channels with the aromatic rings as the exclusive components of the chiral channel walls. The Royal Society of Chemistry 2010.

Efficient macrocyclization of U-turn preorganized peptidomimetics: The role of intramolecular H-bond and solvophobic effects

Simple peptidomimetic molecules derived from amino acids were reacted with meta- and parabis(bromomethyl) benzene in acetonitrile to very efficiently yield macrocyclic structures. The cyclization reaction does not require high dilution techniques and seems to be insensitive to the size of the formed macrocycle. The analysis of data obtained by 1H NMR, single-crystal X-ray diffraction, fluorescence measurements, and molecular mechanics indicate that folded conformations can preorganize the system for an efficient cyclization. The role played by intramolecular hydrogen-bonding and solvophobic effects in the presence of folded conformations is analyzed.

Polyazamacrocycles and their metal complexes

A 13 or 14 member macrocyclic compound having the following ring nucleus: STR1 This work was supported by grants from the National Institutes of Health (GM-34841) and the National Science Foundation (CHE-8706616).

Optically Active Difunctionalized Dioxocyclam Macrocycles: Ligands for Nickel-Catalyzed Oxidation of Alkenes

A general synthetic route has been applied to the synthesis of optically active difunctionalized dioxocyclam macrocycles, (3S,9S)-3,9-dialkyl-1,4,8,11-tetraazacyclotetradecane-5,7-diones, and their chiral tetraamine precursors.Macrocycles 2a-c derived fro

Synthesis of a Chiral Dioxo-Cyclam Derived from L-Phenylalanine and its Application to Olefin Oxidation Chemistry

An optically active dioxo-cyclam macrocycle bearing two benzyl side chains derived from phenylalanine has been synthesized; its Ni(II) complex catalyzes the oxidation of olefins using hypochlorite under phase transfer conditions.

Chiral Diaminodiamide Copper(II) Complexes for the Enantioselective Recognition of Amino Acids: Synthesis of the Ligands and Formation Constants

(S,S)-N,N'-Bis(aminoacyl)ethane and (S,S)-bis(aminoacyl)propanediamines (AA-NN-2 and AA-NN-3, respectively, AA = alanine, phenylalanine, valine) were synthesized as the dihydrochlorides, and their complexes with Cu(II) studied potentiometrically.Since the