84812-04-4

Usage

Chemical structure

The compound has a crown ether ring with several atoms arranged in a ring, and an allyloxymethyl functional group.

Functional group

The allyloxymethyl group is composed of an allyl group connected to a methylene group bonded to an ether oxygen.

Type of compound

It is a macrocyclic compound.

Ability to coordinate

Crown ethers, including 2-(ALLYLOXYMETHYL)-18-CROWN 6-ETHER, are known for their ability to coordinate alkali metal cations.

Potential applications

The compound may have applications in areas such as ion transport and extraction processes.

Further investigation

Its specific properties and potential uses would need to be investigated further through experimental studies.

InChI:InChI=1/C16H30O7/c1-2-3-21-14-16-15-22-11-10-19-7-6-17-4-5-18-8-9-20-12-13-23-16/h2,16H,1,3-15H2

Upstream product

• 123-34-2 3-allyloxy-1,2-propanediol 
• 41024-91-3 penta(ethylene glycol) bis(p-toluenesulfonate) 
• 70069-04-4 2-hydroxymethyl-18-crown-6 
• 106-95-6 allyl bromide 
• 106-92-3 Allyl glycidyl ether 
• 114951-77-8 1-Allyloxy-3-[2-(2-hydroxy-ethoxy)-ethoxy]-propan-2-ol 
• 19249-03-7 triethylene glycol di-(p-toluenesulfonate) 
• 84812-09-9 1-((allyloxy)methyl)-3,6,9-oxa-undecane-1,11-diol 
• 7460-82-4 diethylene glycol ditosylate 
• 4792-15-8 Pentaethylene glycol 

Downstream Products

• 70069-04-4 2-hydroxymethyl-18-crown-6 

Relevant academic research and scientific papers

Crown ether functionalized carbosilane dendrimers

The synthesis of the allyloxymethyl-functionalized crown ethers of type CH2=CHCH2OCH2[15-crown-5] (3a) and CH 2=CHCH2OCH2[18-crown-6] (3b) can be achieved by treatment of HOCH2[1

Polymeric and immobilized crown compounds, material for ion separation

We describe the synthesis of ionoselective polymers bearing different pendant crown ethers. The synthesis was applied to various macrocycles. We discuss the influence of macrocyclic cavity size and rigidity of the polymers on the extraction behavior. Accessibility of active sites can be achievied with immobilized functionalized polyurethanes chemically bound to an inorganic solid support, with no change of ionoselective properties.

Synthesis and Evaluation of New Polyurethane - Based Material for Ion Separation

The polyaddition of macrocyclic diols with diisocyanates is an easy way to prepare ionselective polymers bearing pendant crown ethers.Those polymers can be readily immobilized on silicagel, with no change of ionselective properties.

A CONVENIENT SYNTHESIS OF CROWN AND AZACROWN ETHERS WITH PENDANT OXIRANE GROUP

Synthesis of 4,5-epoxy-2-oxa-1-pentylcrown (I) and N-(2,3-epoxy-1-propyl)azacrown ethers (II) from accessible materials is described.