4792-15-8Relevant articles and documents
Photocatalytic Degradation of Hexaethylene Glycol
Simangoye Ngobissi, Drocilia Ednah,Soufi, Jihène,Vanoye, Laurent,Richard, Dominique
, p. 1608 - 1614 (2017/08/29)
Abstract: Polyethylene glycol (PEG) photodegradation was studied in water under UV irradiation in the presence of catalytic amount of TiO2 using hexaethylene glycol as a model compound. Full conversion was achieved in 7 h with an average quantum yield around 1%. Formic acid was found to be the main intermediate and was slower to oxidize into CO2 (traces remains after 24 h). The other intermediates [lower PEG, oxidized PEG (formates, aldehydes and acids, acetic acid)] of the photodegradation have also been identified and quantified. A mechanism based on previous literature but also taking into account these new observations is proposed. Graphical Abstract: [Figure not available: see fulltext.].
Novel C1-symmetric chiral crown ethers bearing rosin acids groups: Synthesis and enantiomeric recognition for ammonium salts
Liu, Lu-Zhi,He, Chun-Huan,Yang, Lin,Huang, Yan,Wu, Qiang,Duan, Wen-Gui,Wang, Heng-Shan,Pan, Ying-Ming
, p. 9545 - 9553 (2015/03/05)
Four types of novel C1-symmetric chiral crown ethers including 28-crown-8, 20-crown-6, 17-crown-5 and 14-crown-3 (9a-m) were synthesized and their enantiodiscriminating abilities with protonated primary amines (10-14) were examined by 1H NMR spectroscopy. 20-crown-6 crown ethers exhibited good chiral recognition properties toward these guests and showed different complementarity to some chiral guests, indicating that 20-crown-6 crown ethers could be used as a chiral NMR solvating agent to determine the enantiopurity of these guests. In addition, the binding model and binding site between the hosts and guests were also studied by the computational modeling and experimental calculation.
A Highly Selective Synthesis of Monodisperse Oligo(ethylene glycols)
Keegstra, Erik M. D.,Zwikker, Jan W.,Roest, Martin R.,Jenneskens, Leonardus W.
, p. 6678 - 6680 (2007/10/02)
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