852235-04-2Relevant articles and documents
Anomeric effect on kinetic acidity: Examples for the oxygen atom of ethers to accelerate abstraction of an α-hydrogen atom
Sakakibara, Tohru,Ito, Shinji,Ikegawa, Hiroshi,Matsuo, Ichiro,Seta, Akinori
, p. 3429 - 3432 (1993)
In contrast with general observation, two different types of experiments indicate that the abstraction of α-hydrogen atom of ether having proper conformation is slightly enhanced by the oxygen atom in line with our previous AM1 calculation.