852235-04-2

Basic information

• Product Name: (2R,4aR,7S,8aS)-2-Phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol
• CAS NO: 852235-04-2
• Molecular Weight: 236.268
• Mol File: 852235-04-2.mol

Chemical Properties

• CAS DataBase Reference: (2R,4aR,7S,8aS)-2-Phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4aR,7S,8aS)-2-Phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol(852235-04-2)
• EPA Substance Registry System: (2R,4aR,7S,8aS)-2-Phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol(852235-04-2)

Safety Data

• Hazardous Substances Data: 852235-04-2(Hazardous Substances Data)

Upstream product

• 164105-30-0 4,6-O-benzylidene-1,5:2,3-dianhydro-D-mannitol 
• 150571-93-0 1,5-anhydro-2,3-dideoxy-4,6-O-(phenylmethylene)-D-erythro-hex-1-enitol 

Downstream Products

• 150653-80-8 Methanesulfonic acid (2R,4aR,7R,8aS)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 149312-20-9 1',5'-anhydro-4,6-O-benzylidene-3-deoxy-D-glucitol 
• 76231-50-0 (2R,4aR,8aS)-2-Phenyl-4,4a,8,8a-tetrahydro-pyrano[3,2-d][1,3]dioxine 
• 150571-93-0 1,5-anhydro-2,3-dideoxy-4,6-O-(phenylmethylene)-D-erythro-hex-1-enitol 
• 150571-95-2 Methanesulfonic acid (2R,4aR,7S,8aS)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 

Relevant articles and documents

Anomeric effect on kinetic acidity: Examples for the oxygen atom of ethers to accelerate abstraction of an α-hydrogen atom

In contrast with general observation, two different types of experiments indicate that the abstraction of α-hydrogen atom of ether having proper conformation is slightly enhanced by the oxygen atom in line with our previous AM1 calculation.