Anomeric effect on kinetic acidity: Examples for the oxygen atom of ethers to accelerate abstraction of an α-hydrogen atom

DOI: 10.1016/S0040-4039(00)79174-X

Source and publish data:

Tetrahedron Letters p. 3429 - 3432 (1993)

Update date:2022-07-29

Topics:

Authors:

Sakakibara, Tohru

Ito, Shinji

Ikegawa, Hiroshi

Matsuo, Ichiro

Seta, Akinori

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Article abstract of DOI:10.1016/S0040-4039(00)79174-X

In contrast with general observation, two different types of experiments indicate that the abstraction of α-hydrogen atom of ether having proper conformation is slightly enhanced by the oxygen atom in line with our previous AM1 calculation.

Full text of DOI:10.1016/S0040-4039(00)79174-X

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