85385-06-4

Basic information

• Product Name: Benzenamine, N-(2-methoxy-1-methylethylidene)-2,6-dimethyl-
• CAS NO: 85385-06-4
• Molecular Formula: C12H17NO
• Molecular Weight: 191.273
• Mol File: 85385-06-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(2-methoxy-1-methylethylidene)-2,6-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(2-methoxy-1-methylethylidene)-2,6-dimethyl-(85385-06-4)
• EPA Substance Registry System: Benzenamine, N-(2-methoxy-1-methylethylidene)-2,6-dimethyl-(85385-06-4)

Safety Data

• Hazardous Substances Data: 85385-06-4(Hazardous Substances Data)

Upstream product

• 13169-00-1 Methoxyallene 
• 87-62-7 2,6-dimethylaniline 
• 5878-19-3 Methoxyacetone 

Downstream Products

• 118604-66-3 (R)-N-(1-methyl-2-methoxyethyl)-2,6-dimethylaniline 
• 118604-67-4 S-2,6-dimethyl-N-(2-methoxy-1-methylethyl)-aniline 
• 51219-00-2 (R)-2-ethyl-N-(1-methoxypropan-2-yl)-6-methylaniline 
• 118604-70-9 (S)-2-ethyl-N-(1-methoxypropan-2-yl)-6-methylaniline 
• 60148-77-8 N-(2',6'-dimethylphenyl)-1-methoxymethylethylamine 

Relevant articles and documents

Chiral phosphine-phosphoramidite ligands for highly efficient Ir-catalyzed asymmetric hydrogenation of sterically hindered N-arylimines

A mild and general iridium-catalyzed, highly enantioselective hydrogenation of sterically hindered N-arylimines with a new H8-BINOL-derived phosphine-phosphoramidite ligand has been developed. The present catalytic system features high turnover numbers (up to 100000) and good to perfect enantioselectivities (up to 99% ee) for the hydrogenation of a variety of sterically hindered N-arylimines.

Chiral organic catalysts for the stereoselective reduction of carbon-nitrogen double bonds for the preparation of enantiomerically enriched amines

The invention relates to compounds of general formula (I): wherein R1-R7 are as defined in the description for use as catalysts in the stereoselective reduction of imines in the presence of trichlorosilane as reducing agent.

Asymmetric hydrogenation method of a ketonic compound and derivative

The present invention relates to a process for the asymmetric hydrogenation of a ketonic compound and derivative. The invention relates to the use of optically active metal complexes as catalysts for the asymmetric hydrogenation of a ketonic compound and derivative. The process for the asymmetric hydrogenation of a ketonic compound and derivative is characterized in that the asymmetric hydrogenation of said compound is carried out in the presence of an effective amount of a metal complex comprising as ligand an optically active diphosphine corresponding to one of the following formulae: STR1