855282-04-1Relevant articles and documents
Studies toward the asymmetric synthesis of the right part of the mycalamides
Zhong, H. Marlon,Sohn, Jeong-Hun,Rawal, Viresh H.
, p. 386 - 397 (2007/10/03)
Described herein is the asymmetric synthesis of a functionalized, trioxadecalin unit that comprises the right-hand part of the mycalamides and related natural products. The synthetic route involves a 16-step sequence that accomplishes the formation of two
Total synthesis of mycalamide A
Sohn, Jeong-Hun,Waizumi, Nobuaki,Zhong, H. Marion,Rawal, Viresh H.
, p. 7290 - 7291 (2007/10/03)
This communication describes a concise and efficient total synthesis of mycalamide A by the convergent coupling of pederic acid unit with the mycalamine unit. The left-half, (+)-7-benzoylpederic acid, was synthesized from (2R,3R)-3-methylpent-4-en-2-ol in