855282-22-3

Upstream product

• 855282-51-8 tert-Butyl-((2R,3R,4S)-4-methoxy-2,3-bis-methoxymethoxy-5,5-dimethyl-hept-6-enyloxy)-diphenyl-silane 
• 937166-60-4 (2S,3S)-4-(tert-butyl(diphenyl)silyloxy)-2,3-bis(methoxymethoxy)butan-1-ol 
• 937166-57-9 (2R,3S)-4-(tert-Butyl-diphenyl-silanyloxy)-2,3-bis-methoxymethoxy-butyraldehyde 
• 877373-78-9 (2R,3R)-4-(tert-Butyl-diphenyl-silanyloxy)-2,3-bis-methoxymethoxy-butan-1-ol 
• 877373-38-1 (2S,3R)-2,3-bis(methoxymethoxy)-4-[(1,1-dimethylethyl)diphenylsilyl]oxybutyraldehyde 
• 855282-04-1 (4S,5R,6R)-5,6-bis(methoxymethoxy)-3,3-dimethyl-7-[(1,1-dimethylethyl)diphenylsilyl]oxy-4-hydroxy-1-heptene 

Downstream Products

• 1054641-55-2 (4S,5S,6R)-6-benzyloxy-5,7-dihydroxy-3,3-dimethyl-4-methoxy-1-heptene 
• 925222-17-9 (4S,5S,6R)-6-benzyloxy-3,3-dimethyl-5,7-O-isopropylidene-4-methoxy-1-heptene 
• 925222-05-5 (4S,5S,6R)-5-benzyloxy-3,3-dimethyl-7-[(1,1-dimethylethyl)diphenylsilyl]oxy-4-methoxy-6-hydroxy-1-heptene 
• 925222-06-6 (2R,3R,4S,6R)-6-(bromomethyl)-2-[(tert-butyldiphenylsilyloxy)methyl]-4-methoxy-5,5-dimethyltetrahydro-2H-pyran-3-yl benzoate 
• 925222-04-4 (4S,5S,6R)-5-benzyloxy-3,3-dimethyl-7-[(1,1-dimethylethyl)diphenylsilyl]oxy-4-methoxy-6-(trimethylsilyl)oxy-1-heptene 
• 855282-57-4 Benzoic acid (1R,2R,3S)-1-(tert-butyl-diphenyl-silanyloxymethyl)-3-methoxy-2-methoxymethoxy-4,4-dimethyl-hex-5-enyl ester 
• 855282-02-9 (((2R,3R,4S,6R)-6-allyl-tetrahydro-4-methoxy-3-(methoxymethoxy)-5,5-dimethyl-2H-pyran-2-yl)methoxy)(tert-butyl)diphenylsilane 
• 855282-24-5 (2R,3S,4S)-1-(tert-Butyl-diphenyl-silanyloxy)-4-methoxy-3-methoxymethoxy-5,5-dimethyl-hept-6-en-2-ol 
• 925222-03-3 (4S,5S,6R)-3,3-dimethyl-7-[(1,1-dimethylethyl)diphenylsilyl]oxy-5-hydroxy-4-methoxy-6-(trimethylsilyl)oxy-1-heptene 

Relevant academic research and scientific papers

Studies toward the asymmetric synthesis of the right part of the mycalamides

Described herein is the asymmetric synthesis of a functionalized, trioxadecalin unit that comprises the right-hand part of the mycalamides and related natural products. The synthetic route involves a 16-step sequence that accomplishes the formation of two

Total synthesis of mycalamide A

This communication describes a concise and efficient total synthesis of mycalamide A by the convergent coupling of pederic acid unit with the mycalamine unit. The left-half, (+)-7-benzoylpederic acid, was synthesized from (2R,3R)-3-methylpent-4-en-2-ol in