85654-07-5

Basic information

• Product Name: N-(TriMethylsilyl)-4-chlorobenzaldiMine
• Synonyms: N-(TriMethylsilyl)-4-chlorobenzaldiMine
• CAS NO: 85654-07-5
• Molecular Formula: C₁₀H₁₄ClNSi
• Molecular Weight: 211.76336
• Mol File: 85654-07-5.mol
• Article Data: 10

Chemical Properties

• Melting Point: 27-36°C
• Flash Point: 54℃
• Appearance: /
• CAS DataBase Reference: N-(TriMethylsilyl)-4-chlorobenzaldiMine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(TriMethylsilyl)-4-chlorobenzaldiMine(85654-07-5)
• EPA Substance Registry System: N-(TriMethylsilyl)-4-chlorobenzaldiMine(85654-07-5)

Safety Data

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26-36/39
• RIDADR: UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., H
• WGK Germany: 2
• Hazardous Substances Data: 85654-07-5(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 4039-32-1 lithium hexamethyldisilazane 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Downstream Products

• 75896-89-8 (4-chlorobenzylidene)(pyridin-3-yl)amine 
• 1026336-55-9 {1-[3-(4-Carbamimidoyl-benzoylamino)-3-(4-chloro-phenyl)-2,2-dimethyl-propionyl]-piperidin-4-yl}-acetic acid benzyl ester 
• 208397-09-5 {1-[3-(4-Chloro-phenyl)-3-(4-cyano-benzoylamino)-2,2-dimethyl-propionyl]-piperidin-4-yl}-acetic acid benzyl ester 
• 208397-02-8 3-(N-4-cyanobenzoyl)amino-2,2-dimethyl-3-(4-chlorophenyl)propionic acid 
• 21161-20-6 1-tert-butoxycarbonyl-2-(4'-chloro)phenylazetidine 
• 269716-25-8 1-chloro-2-(trimethylsilyl)oxy-3-aza-4-p-chloro-phenyl-1,3-butadiene 
• 74788-46-8 1-(4-chlorophenyl)propan-1-amine 
• 180264-45-3 4-(4-chlorophenyl)-3,3-dimethyl-2-azetidinone 
• 199604-20-1 N-methoxycarbonyl-4-chlorobenzaldimine 
• 1609691-78-2 N-((1R,2S)-2-bromo-1-(4-chlorophenyl)-2-nitroethyl)acetamide 
• 1609691-37-3 N-((1R,2R)-2-bromo-1-(4-chlorophenyl)-2-nitroethyl)acetamide 
• 1609691-43-1 allyl N-[(1R,2R)-2-bromo-1-(4-chlorophenyl)-2-nitroethyl]carbamate 
• 1609691-84-0 allyl N-[(1R,2S)-2-bromo-1-(4-chlorophenyl)-2-nitroethyl]carbamate 

Relevant articles and documents

Catalytic enantioselective one-pot aminoborylation of aldehydes: A strategy for construction of nonracemic α-amino boronates

We report a strategy for the conversion of aldehydes to enantiomerically enriched α-amino boronates through the intermediacy of in situ-generated silylimines. This transformation is brought about by Pt-catalyzed asymmetric addition of B2(pin)s

Asymmetric synthesis of propargylamides via 3,3′-disubstituted binaphthol-modified alkynylboronates

(Chemical Equation Presented) Alkynylboronates derived from 3,3′-disubstituted-2,2′-binaphthols react with various N-acylimines to give the expected chiral propargylamides with up to 99% ee. This new methodology was applied to the first enantioselective s

A trans-stereoselective synthesis of 3-halo-4-alkyl(aryl)-NH-azetidin-2-ones

Conrotatory ring closure of 1-halo-3-aza-4-alkyl-1,3-dienes in refluxing toluene gives rise to 3-halo-4-aryl-2-azetidinones in satisfactory yields. Dehalogenation of the resulting β-lactams by tris(trimethylsilyl)silane furnished 3-unsubstituted azetidino