N-(Trimethylsilyl)-4-chlorobenzaldimine

Base Information

• Chemical Name: N-(Trimethylsilyl)-4-chlorobenzaldimine
• CAS No.: 85654-07-5
• Molecular Formula: C10H14ClNSi
• Molecular Weight: 211.766
• European Community (EC) Number: 632-920-9
• Mol file: 85654-07-5.mol

Synonyms:N-(Trimethylsilyl)-4-chlorobenzaldimine;85654-07-5;1-(4-Chlorophenyl)-N-(trimethylsilyl)methanimine;N-(Trimethylsilyl)-4-chlorobenzaldimine, 95%;(E)-1-(4-chlorophenyl)-N-trimethylsilylmethanimine

Chemical Property of N-(Trimethylsilyl)-4-chlorobenzaldimine

Chemical Property:

• Melting Point: 27-36°C
• Flash Point: 54℃
• PSA: 12.36000
• LogP: 3.59380
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 211.0584037
• Heavy Atom Count: 13
• Complexity: 178

Purity/Quality:

98%Min ^*data from raw suppliers

N-(Trimethylsilyl)-4-chlorobenzaldimine 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 26-36/39

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)N=CC1=CC=C(C=C1)Cl
• Isomeric SMILES: C[Si](C)(C)/N=C/C1=CC=C(C=C1)Cl

Technology Process of N-(Trimethylsilyl)-4-chlorobenzaldimine

There total 2 articles about N-(Trimethylsilyl)-4-chlorobenzaldimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

4-chlorobenzaldehyde (104-88-1) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → N-(4-chlorobenzylidene)-N-(1,1,1-trimethylsilyl)amine (85654-07-5)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; hexane; 1.) 0 deg C, 10 min, 2.) r.t., 1 h;

DOI:10.1002/chem.19970031019

Reference yield:

4-chlorobenzaldehyde (104-88-1) + lithium hexamethyldisilazane (4039-32-1) → N-(4-chlorobenzylidene)-N-(1,1,1-trimethylsilyl)amine (85654-07-5)

Guidance literature:

In diethyl ether; at -30 ℃; for 0.5h;

DOI:10.1021/jo971061r

Reference yield: 97.0%

dimethyl acetylenedicarboxylate (762-42-5) + N-(4-chlorobenzylidene)-N-(1,1,1-trimethylsilyl)amine (85654-07-5) → (Z)-2-{[1-(4-Chloro-phenyl)-meth-(E)-ylidene]-amino}-3-trimethylsilanyl-but-2-enedioic acid dimethyl ester

Guidance literature:

In toluene; at 25 ℃; for 4h;

DOI:10.1039/c39870001195

upstream raw materials:

4-chlorobenzaldehyde

1,1,1,3,3,3-hexamethyl-disilazane

lithium hexamethyldisilazane

Downstream raw materials:

N-methoxycarbonyl-4-chlorobenzaldimine

4-(4-chlorophenyl)-3,3-dimethyl-2-azetidinone

1-(4-chlorophenyl)propan-1-amine

1-chloro-2-(trimethylsilyl)oxy-3-aza-4-p-chloro-phenyl-1,3-butadiene

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