86040-00-8Relevant academic research and scientific papers
A ring-closing metathesis (RCM)-based approach to mycolactonesa A/B
Gersbach, Philipp,Jantsch, Andrea,Feyen, Fabian,Scherr, Nicole,Dangy, Jean-Pierre,Pluschke, Gerd,Altmann, Karl-Heinz
, p. 13017 - 13031 (2012/01/02)
The total synthesis of the mycobacterial toxins mycolactones A/B (1 a/b) has been accomplished based on a strategy built around the construction of the mycolactone core through ring-closing metathesis. By employing the Grubbs second-generation catalyst, t
New approaches towards the synthesis of the side-chain of mycolactones A and B
Van Summeren, Ruben P.,Feringa, Ben L.,Minnaard, Adriaan J.
, p. 2524 - 2533 (2007/10/03)
New approaches towards the synthesis of the C1′-C16′ side-chain of mycolactones A and B from Mycobacterium ulcerans are reported. Chiral building block 4 (Fig. 2) with the correct stereochemistry was obtained starting from naturally occurring monosacchari
Chiral Building Units from Carbohydrates, VIII. - Syntheses of the Four Isomeric 1,3-Dimethyl-2,9-dioxabicyclononanes
Redlich, Hartmut,Schneider, Bernd,Hoffmann, Reinhard W.,Geueke, Karl-Josef
, p. 393 - 411 (2007/10/02)
Starting from different compounds, the syntheses of the four isomeric bicyclic acetals 17, 32, 36, and 40 - the title compounds - are described.One of these compounds is supposed to direct the attack of the striped ambrosia beetle Trypodendron lineatum Ol
