860590-06-3

Upstream product

• 577-19-5 2-nitrophenyl bromide 
• 939-80-0 4-chloro-3-nitrobenzonitrile 
• 88-73-3 2-Chloronitrobenzene 
• 1454-80-4 1,1'-biphenyl-2,2'-diamine 
• 16588-06-0 4-chloro-3-nitrobenzamide 
• 860563-65-1 3,3'-dinitro-4,4'-biphenyl-2,2'-diyldiamino-di-benzonitrile 
• 859942-99-7 3,3'-diamino-4,4'-biphenyl-2,2'-diyldiamino-di-benzonitrile 
• 623-03-0 4-Cyanochlorobenzene 
• 860561-80-4 3,3'-diamino-4,4'-biphenyl-2,2'-diyldiamino-di-benzoic acid 
• 860590-00-7 N,N'-bis-(2-nitro-phenyl)-biphenyl-2,2'-diyldiamine 
• 38818-50-7 4-chloro-3-nitro-benzoyl chloride 

Relevant academic research and scientific papers

Synthesis of new NHC-rhodium and iridium complexes derived from 2,2′-diaminobiphenyl and their catalytic activities toward hydrosilylation of ketones

Four new N-heterocyclic carbene (NHC)-rhodium and iridium complexes derived from 2,2′-diaminobiphenyl have been successfully synthesized and their structures have been unambiguously characterized by X-ray diffraction. Their catalytic activities for hydrosilylation of ketones with diphenylsilane were investigated. It was found that NHC-rhodium complex (6) is the best one among the four catalysts for the reduction of ketones.