861083-81-0

Basic information

• Product Name: (4-iodophenyl)(4-methoxyphenyl)thioether
• Synonyms: (4-iodophenyl)(4-methoxyphenyl)thioether
• CAS NO: 861083-81-0
• Molecular Weight: 342.2
• Mol File: 861083-81-0.mol

Chemical Properties

• CAS DataBase Reference: (4-iodophenyl)(4-methoxyphenyl)thioether(CAS DataBase Reference)
• NIST Chemistry Reference: (4-iodophenyl)(4-methoxyphenyl)thioether(861083-81-0)
• EPA Substance Registry System: (4-iodophenyl)(4-methoxyphenyl)thioether(861083-81-0)

Safety Data

• Hazardous Substances Data: 861083-81-0(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 696-63-9 4-Methoxybenzenethiol 
• 62830-55-1 2-(4-iodophenyl)hydrazin-1-ium chloride 
• 2751-27-1 4-iodobenzenesulfonyl hydrazide 
• 5720-07-0 4-methoxyphenylboronic acid 
• 100-00-5 4-chlorobenzonitrile 
• 22865-50-5 4-(4-methoxyphenylsulfanyl)nitrobenzene 
• 106-53-6 para-bromobenzenethiol 
• 125662-16-0 (4’-bromophenyl)(4-methoxyphenyl)sulfane 
• 14453-85-1 4-[(4-methoxyphenyl)thio]benzenamine 

Downstream Products

• 865179-26-6 1-(4-methoxyphenylthio)-4-(4-iodophenylthio)benzene 
• 865179-24-4 1-(4-methoxyphenylthio)-4-(4-bromophenylthio)benzene 

Relevant articles and documents

Palladium-Catalyzed Oxidative Cross-Coupling of Arylhydrazines and Arenethiols with Molecular Oxygen as the Sole Oxidant

A highly efficient palladium-catalyzed oxidative cross-coupling of arylhydrazines and arenethiols with molecular oxygen as the sole oxidant to afford unsymmetrical diaryl sulfides has been developed. The only byproducts are nitrogen and water. A broad range of functional groups, even the reactive iodides, are tolerated and thus offer the opportunity for further functionalization.

Synthesis of molecular chains: Application of cross-coupling and bromo by iodo exchange reactions

The synthesis of a series of molecular chains by use of C-S, C-N and C-Alkyne cross coupling, as well as bromo by iodo exchange reactions, has been reported. Two different types of chains R-C6H4-S-C6H4-CC-C6H4-NH-C6H4-Br, and R-C6H4-S-C6H4-NH-C6H4-CC-C6H4-Br (R=MeO, CN, NO2) could be obtained starting from the same thioether but applying different reaction sequences. Compounds R-C6H4-CC-C6H4-S-C6H4-NH-C6H4-Br were prepared from diaryl acetylenes after two bromo by iodo replacements alternated with a C-S and a C-N cross coupling.

Copper-catalyzed sulfenylation of boronic acids with sulfonyl hydrazides

An unprecedented sulfenylation reaction of carbon-boron bonds has been developed using sulfonyl hydrazides as sulfenyl sources. A range of sulfonyl hydrazides underwent tetrakis(acetonitrile)copper(I) tetrafluoroborate [Cu(CH3CN)4BF4]/2,2′-bipyridine-catalyzed sulfenylation with boronic acids under air to give structurally diverse thioethers in moderate to good yields. Preliminary mechanistic studies show that sulfonyl hydrazides are subjected to decomposition into thiosulfonates and disulfides followed by formation of carbon-sulfur bonds with boronic acids.

A new approach to the synthesis of oligomers. Application to the synthesis of p-phenylene thioether wires

Oligothioethers 4-RC6H4(SC6H 4-4)nX (n = 1-3; X = Br, I; R = NO2; X = Br; R = MeO. n = 1 and 2; X = I; R = MeO. n = 4; X = Br; R = NO2) have been prepared through a process invol