863092-97-1

Upstream product

• 108454-55-3 3-(4-methoxyphenyl)-2-butenoic acid ethyl ester 
• 93397-63-8 2-(4-methoxyphenyl)propan-1-ol 
• 19493-09-5 Methylenetriphenylphosphorane 
• 460323-49-3 2-(4-methoxy-phenyl)-2-methyl-5-methylene-cyclopentanol 
• 460323-46-0 (E)-5-(4-Methoxy-phenyl)-hex-3-en-2-one 
• 34399-55-8 5-(4-methoxy-phenyl)-hexan-2-one 
• 50415-73-1 methyl 2-(4-methoxyphenyl)propionate 
• 23786-14-3 4-methoxy-phenyl acetic acid methyl ester 
• 252058-33-6 2-(4-methoxyphenyl)propanal 
• 862982-78-3 3-(4-methoxyphenyl)-3-methyl-pent-4-en-1-ol 
• 149520-42-3 3-(4-methoxyphenyl)-but-2-en-1-ol 
• 863093-00-9 toluene-4-sulfonic acid 3-(4-methoxy-phenyl)-3-methyl-pent-4-enyl ester 
• 862982-44-3 ethyl 3-(4-methoxyphenyl)-3-methylpent-4-enoate 
• 863092-96-0 4-(4-methoxyphenyl)-4-methyl-hex-5-enonitrile 

Downstream Products

• 1220126-44-2 C₁₅H₂₀O₃ 
• 235101-23-2 methyl (R)-(-)-4-(4-methoxyphenyl)-4-methylhex-5-enoate 
• 223691-88-1 1-(1,5-dimethyl-1-vinyl-hex-4-enyl)-4-methoxy-benzene 
• 223691-84-7 4-(4-methoxyphenyl)-4-methyl-hex-5-en-1-al 
• 401895-10-1 4-(4-methoxy-phenyl)-4-methyl-hex-5-en-1-ol 

Relevant academic research and scientific papers

A new powerful strategy for the organocatalytic asymmetric construction of a quaternary carbon stereogenic center

(Figure Presented) A new method for chiral diamine-catalyzed Robinson-type annulation was developed to construct cyclohexenone derivatives bearing a quaternary carbon stereogenic center at the 4-position in high enantiomeric excess. This method was successfully applied to the short synthesis of (+)-sporochnol A.

Synthesis of sporochnol A, a marine fish deterrent

A synthesis of the methyl ether of the fish-deterrent sporochnol A is described. The route involves the application of Claisen ortho-ester rearrangement to generate the key quaternary carbon. Copyright Taylor & Francis, Inc.

Total synthesis of sporochnols, fish deterrents from a marine alga

Sporochnols, fish deterrents from a marine alga, were synthesized, using intramolecular C-H insertion of alkylidenecarbene as a key step to construct the chiral quaternary center.