86622-84-6

Basic information

• Product Name: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER
• Synonyms: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER
• CAS NO: 86622-84-6
• Molecular Formula: C₁₃H₁₅NO₄
• Molecular Weight: 249.2625
• Mol File: 86622-84-6.mol
• Article Data: 242

Chemical Properties

• Boiling Point: 355.13°C at 760 mmHg
• Flash Point: 143.705°C
• Appearance: /
• Density: 1.177g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER(86622-84-6)
• EPA Substance Registry System: (E)-3-(4-NITRO-PHENYL)-ACRYLIC ACIDBUTYL ESTER(86622-84-6)

Safety Data

• Hazardous Substances Data: 86622-84-6(Hazardous Substances Data)

Usage

General Description

(E)-3-(4-nitro-phenyl)-acrylic acid butyl ester is a chemical compound with the molecular formula C14H15NO4. It is an ester derivative of (E)-3-(4-nitro-phenyl)-acrylic acid, which is a yellow crystalline solid with a molecular weight of 257. The butyl ester form of this compound is commonly used in the preparation of various organic compounds and can be used as a starting material for the synthesis of pharmaceuticals, agrochemicals, and other fine chemicals. It is also used in organic chemical synthesis and as a reagent in various chemical reactions due to its unique structural and chemical properties. Additionally, (E)-3-(4-nitro-phenyl)-acrylic acid butyl ester is known for its potential and proven applications in the field of material science and biochemistry.

InChI:InChI=1/C13H15NO4/c1-2-3-10-18-13(15)9-6-11-4-7-12(8-5-11)14(16)17/h4-9H,2-3,10H2,1H3/b9-6+

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Downstream Products

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Relevant articles and documents

Reusable, magnetic Raney nickel based palladium catalysts for the Heck coupling in aqueous media

Hybrid materials based on Pd- and Cu-doped Raney nickel appeared to be highly efficient catalysts for the Heck reaction in aqueous media in the absence of organic cosolvents. The catalysts can be easily removed by an external magnet and reused without losing catalytic activity.

Fe-MIL-101 modified by isatin-Schiff-base-Co: a heterogeneous catalyst for C-C, C-O, C-N, and C-P cross coupling reactions

A metal-organic framework functionalized with a cobalt-complex is preparedviapost-synthetic modification of Fe-MIL-101-NH2. Initially, Fe-MIL-101-NH2reacted with isatin to produce Fe-MIL-101-isatin-Schiff-base, which can anchor the cobalt by the addition of cobalt acetate. The resulting MOF-Co catalyst is characterized by employing multiple techniques. This new modified MOF acts as a heterogeneous and recyclable catalyst for efficient Ullmann, Buchwald-Hartwig, Hirao, Hiyama and Mizoroki-Heck cross-coupling reactions of several aryl halides/phenylboronic acid/phenyltosylate with phenols, anilines/heterocyclic amines, triethyl phosphite, triethoxyphenylsilane and alkenes and generates the expected coupling products in good to high yields.

Palladium supported aminobenzamide modified silica coated superparamagnetic iron oxide as an applicable nanocatalyst for Heck cross-coupling reaction

An applicable palladium-based nanocatalyst was constructed through the immobilization of palladium onto 2-aminobenzamide functionalized silica coated superparamagnetic iron oxide magnetic nanoparticles. The nanocatalyst (named as Pd@ABA@SPIONs@SiO2) was characterized by several characterization methods, including scanning electron microscope (SEM), transmission electron microscopy (TEM), vibrating-sample magnetometry (VSM), energy-dispersive X-ray spectroscopy (EDS), dynamic light scattering (DLS), X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), inductively coupled plasma (ICP), and X-ray photoelectron spectroscopy (XPS) analyses. Microscopy results showed that the nanoparticles are spherical in shape with 20–25 nm size. The size of the nanoparticles was confirmed by the DLS method. The superparamagnetic nature of the catalyst was confirmed by the VSM method. The successful functionalization of SPIONs@SiO2 was confirmed by FT-IR spectroscopy. The presence of palladium in the structure of the nanocatalyst was illustrated by XRD and EDS analysis. Also using XPS technique, the oxidation state of palladium in Pd@ABA@SPIONs@SiO2 was determined zero before and after the catalyst was applied in Mizoroki-Heck reaction. Several aryl halides and alkenes were reacted in the presence of the nanocatalyst and formed the corresponding products in high isolated yields. The nanocatalyst showed very good reusability and did not decrease its activity after 10 sequential runs. Density functional theory (DFT) calculation was performed to provide a mechanism for the reaction and confirmed the role of the palladium catalyst in the reaction function.