86652-64-4

Upstream product

• 82725-38-0 N-(2-benzyloxyphenyl)formamide 
• 20012-63-9 o-(benzyloxy)aniline 
• 88-75-5 2-hydroxynitrobenzene 
• 100-39-0 benzyl bromide 
• 4560-41-2 2-benzyloxynitrobenzene 
• 64-18-6 formic acid 

Downstream Products

• 872599-78-5 2-{(3R,6R)-3-(2,3-dihydro-1H-inden-2-yl)-6-[(1S)-1-methylpropyl]-2,5-dioxo-1-piperazinyl}-2-(4,6-dimethyl-3-pyridinyl)-N-{2-[(phenylmethyl)oxy]phenyl}acetamide 
• 1009810-28-9 C₄₅H₄₈N₄O₈ 
• 820957-43-5 2-((2R,5R)-2-((S)-sec-butyl)-5-(2,3-dihydro-1H-inden-2-yl)-3,6-dioxopiperazin-1-yl)-N-(2-hydroxyphenyl)-2-(2-methyloxazol-4-yl)acetamide 
• 1286784-65-3 C₄₂H₅₂N₄O₅ 
• 872599-76-3 methyl N-[(2R)-2-(2,3-dihydro-1H-inden-2-yl)-2-({[(phenylmethyl)oxy]-carbonyl}amino)acetyl]-N-[1-(2,6-dimethyl-3-pyridinyl)-2-oxo-2-({2-[(phenylmethyl)oxy]phenyl}amino)ethyl]-D-alloisoleucinate 

Relevant academic research and scientific papers

A novel method for preparing isocyanides from N-substituted formamides with chlorophosphate compounds

Treatment of N-substituted formamides with chlorophosphate compounds such as PhOPOCl2, EtOPOCl2, Me2NPOCl2, and (PhO)2POCl and tertiary amines such as triethylamine, pyridine, and N,N-diisopropylethylamine produced the corresponding isocyanides in high yields. This method can be used to prepare various alkyl and aryl isocyanides. Georg Thieme Verlag Stuttgart · New York.

Total syntheses of Tardioxopiperazine A, Isoechinulin A, and Variecolorin C

Chemical equations presented. First total syntheses of the isoechinulin-type alkaloids: Tardioxopiperazine A, Isoechinulin A, and Variecolorin C have been achieved from a common key intermediate 5, which was derived from a regiocontrolled Stille cross-coupling reaction of an allylindium reagent.