87168-59-0

Upstream product

• 100-42-5 styrene 
• 26577-95-7 bis-(3-methoxycarbonyl-propionyl)-peroxide 
• 75-05-8 acetonitrile 
• 934520-52-2 5-hydroxyimino-5-phenylpentanoic acid methyl ester 
• 1501-05-9 5-oxo-5-phenylvaleric acid 
• 1501-04-8 Methyl 4-benzoylbutanoate 
• 1266186-39-3 methyl (4E)-5-(N-acetylamino)-5-phenylpent-4-enoate 
• 24549-33-5 C₁₀H₁₂ClHgNO 
• 292638-85-8 acrylic acid methyl ester 

Relevant academic research and scientific papers

Method for synthesizing amide compound

The invention discloses a method for the synthesizing a compound as shown in a formula I which is described in the specification. The method comprises a step of subjecting a compound II, a compound III and a compound IV to reaction in the presence of a catalyst to form the compound as shown in the formula I, wherein the compound II is one selected from compounds as shown in a formula II; the compound III is at least one selected from compounds as shown in a formula III-1 and a formula III-2; the compound IV is one selected from compounds as shown in a formula IV; R3 and R4 are independently selected from a group consisting of an alkyl group, a substituted alkyl group, a heteroaryl group and a substituted heteroaryl group.

Stereocontrolled approach to δ-amino acids by asymmetric hydrogenation of 5-acetylaminopent-4-enoic acid derivatives

Asymmetric hydrogenation of the C=C bond in 5-acetylamino-5-phenylpent-4- enoic acid methyl ester or N,N-dimethylamide catalyzed by rhodium complexes with chiral bisphosphine ligands (1 mol.% of the catalyst, 20 atm. of H2, MeOH, 50°C) gives the correspon

Efficient Coupling Reactions of β-Amino and β-Acetamido Radicals with Electron Deficient Alkenes - Aza-Carbofunctionalization of Olefins - A Promising New Tool for Alkaloid Synthesis.

The coupling reactions of β-amino and β-acetamido radicals prepared by reduction of organomercurials have been examined as a potentially new approach to alkaloid construction.