88151-72-8Relevant academic research and scientific papers
N-heterocyclic carbenes mediated cyano-phosphorylation of ketones
He, Lin,Zhang, Jing,Fan, Ye-Cheng,Du, Guang-Fen,Zhang, Jie,Dai, Bin
supporting information, p. 5861 - 5864 (2013/10/21)
Cyanation-O-protection reaction of ketones with different cyanide sources catalyzed by N-heterocyclic carbenes is reported. Under the catalysis of 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene, various ketones coupled with diethyl cyanophosphonate to p
A convenient and improved preparation of Cyano phosphates
Mico, Irene,Najera, Carmen
, p. 4327 - 4332 (2007/10/02)
Cyano phosphates derived from aldehydes or ketones are prepared in good yields using lithium cyanide in DMF and diethyl chlorophosphate as phosphorylating agent.
Application of Cyanophosphates in Organic Synthesis. Reactivity of α-Cyano-α-diethylphosphonooxy Anions
Kurihara, Takushi,Santo, Kazunori,Harusawa, Shinya,Yoneda, Ryuji
, p. 4777 - 4788 (2007/10/02)
The utility of the cyanohydrin diethylphosphates derived from aldehydes (arylaldehydes,crotonaldehyde, and cinnamaldehyde) as an acyl anion equivalent was examined.Deprotonation of cyanophosphates with n-butyllithium in the presence of tetramethylethylene
A NEW SYNTHESIS OF SOME NON-STEROIDAL ANTI-INFLAMMATORY AGENTS VIA CYANOPHOSPHATES
Hurusawa, Shinya,Nakamura, Shuji,Yagi, Sayoko,Kurihara, Takushi,Hamada, Yasumasa,Shioiri, Takayuki
, p. 1365 - 1372 (2007/10/02)
A simple and convenient procedure for the syntheses of some non-steroidal anti-inflammatory agents, ibuprofen, rac-naproxen, clidanac and loxoprofen, is described.
CYANOPHOSPHORYLATION OF KETONES AND ALDEHYDES USING DIETHYL PHOSPHOROCYANIDATE (DEPC)
Harusawa, Shinya,Yoneda, Ryuji,Kurihara, Takushi,Hamada, Yasumasa,Shioiri, Takayuki
, p. 2932 - 2935 (2007/10/02)
A novel one-pot and high-yield cyanophosphorylation of carbony compounds is achieved by treatment of ketones or aldehydes with diethyl phosphorocyanidate (DEPC) in the presence of a catalytic amount of lithium diisopropylamide in tetrahydrofuran.KEYWORDS
