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2408-36-8

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2408-36-8 Usage

Chemical Properties

colorless to light yellow liquid; sensitive to moisture; freezing point 58°C [STR93]

Check Digit Verification of cas no

The CAS Registry Mumber 2408-36-8 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,4,0 and 8 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 2408-36:
(6*2)+(5*4)+(4*0)+(3*8)+(2*3)+(1*6)=68
68 % 10 = 8
So 2408-36-8 is a valid CAS Registry Number.
InChI:InChI=1/CN.Li/c1-2;/q-1;+1

2408-36-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name lithium,cyanide

1.2 Other means of identification

Product number -
Other names EINECS 219-308-3

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:2408-36-8 SDS

2408-36-8Synthetic route

hydrogen cyanide
74-90-8

hydrogen cyanide

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
With lithium hydroxide; water
With lithium hydroxide
With diethyl ether; lithium
With lithium; benzene
Ba(CN)2

Ba(CN)2

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
With lithium sulfate
Li

Li

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
Erhitzen unter Ausschluss von Luft;
hydrogen cyanide
74-90-8

hydrogen cyanide

lithium hydroxide

lithium hydroxide

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
With diethyl ether
hydrogen cyanide
74-90-8

hydrogen cyanide

A

lithium cyanide
2408-36-8

lithium cyanide

B

lithium cyanamide

lithium cyanamide

Conditions
ConditionsYield
With lithium at 570℃; im eisernen Gefaess;
ethanedinitrile
460-19-5

ethanedinitrile

A

lithium cyanide
2408-36-8

lithium cyanide

B

lithium cyanamide

lithium cyanamide

Conditions
ConditionsYield
With lithium at 400℃; im eisernen Gefaess;
dilithium acetylide

dilithium acetylide

A

lithium cyanide
2408-36-8

lithium cyanide

B

lithium cyanamide

lithium cyanamide

Conditions
ConditionsYield
With nitrogen
methyl isocyanate
593-75-9, 685498-28-6

methyl isocyanate

lithium
7439-93-2

lithium

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
In gaseous matrix Li and CH3NC with excess inert gas co-condensed for 1 h;
methyl isocyanate
593-75-9, 685498-28-6

methyl isocyanate

lithium
7439-93-2

lithium

A

lithium cyanide
2408-36-8

lithium cyanide

B

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
In gaseous matrix Irradiation (UV/VIS); cocondensation Li and CH3NC with excess inert gas and photolysis with medium pressure Hg lamp;
2-hydroxy-2-methylpropanenitrile
75-86-5

2-hydroxy-2-methylpropanenitrile

lithium cyanide
2408-36-8

lithium cyanide

Conditions
ConditionsYield
With lithium hydride In tetrahydrofuran at 0 - 20℃; for 2h;
lithium cyanide
2408-36-8

lithium cyanide

cyclohexanone
108-94-1

cyclohexanone

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

1-<(tert-butyldimethylsilyl)oxy>-1-cyanocyclohexane
114114-74-8

1-<(tert-butyldimethylsilyl)oxy>-1-cyanocyclohexane

Conditions
ConditionsYield
In tetrahydrofuran for 70h; Ambient temperature;100%
lithium cyanide
2408-36-8

lithium cyanide

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

benzoyl chloride
98-88-4

benzoyl chloride

2-(benzoyloxy)-2-(4-chlorophenyl)acetonitrile
19788-56-8

2-(benzoyloxy)-2-(4-chlorophenyl)acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Ambient temperature;100%
lithium cyanide
2408-36-8

lithium cyanide

3-nitro-benzaldehyde
99-61-6

3-nitro-benzaldehyde

benzoyl chloride
98-88-4

benzoyl chloride

benzoyloxy-(3-nitro-phenyl)-acetonitrile
7252-27-9

benzoyloxy-(3-nitro-phenyl)-acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran for 0.166667h; Ambient temperature;100%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

1-Benzylindole-3-carboxaldehyde
10511-51-0

1-Benzylindole-3-carboxaldehyde

1-benzyl-2-cyano-3-indoleacetonitrile
101690-59-9

1-benzyl-2-cyano-3-indoleacetonitrile

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Ambient temperature;100%
lithium cyanide
2408-36-8

lithium cyanide

1-Benzylindole-3-carboxaldehyde
10511-51-0

1-Benzylindole-3-carboxaldehyde

1-benzyl-2-cyano-3-indoleacetonitrile
101690-59-9

1-benzyl-2-cyano-3-indoleacetonitrile

Conditions
ConditionsYield
With diethyl dicarbonate100%
lithium cyanide
2408-36-8

lithium cyanide

benzoyl chloride
98-88-4

benzoyl chloride

4-Phenylbenzaldehyde
3218-36-8

4-Phenylbenzaldehyde

α-Benzoyloxy-α-(4-biphenylyl)acetonitrile
108583-45-5

α-Benzoyloxy-α-(4-biphenylyl)acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Ambient temperature;100%
lithium cyanide
2408-36-8

lithium cyanide

benzoyl chloride
98-88-4

benzoyl chloride

cyclohexanecarbaldehyde
2043-61-0

cyclohexanecarbaldehyde

benzoic acid cyano(cyclohexyl)methyl ester
108583-50-2

benzoic acid cyano(cyclohexyl)methyl ester

Conditions
ConditionsYield
In tetrahydrofuran for 0.5h; Ambient temperature;100%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

2-deoxy-3,5-di-O-benzyl-β-D-ribofuranosylcarbaldehyde

2-deoxy-3,5-di-O-benzyl-β-D-ribofuranosylcarbaldehyde

lithium cyanide
2408-36-8

lithium cyanide

diethylphosphonooxy-(3,5-bis-O-benzyl-2-deoxy-β-ribofuranosyl)-acetonitrile

diethylphosphonooxy-(3,5-bis-O-benzyl-2-deoxy-β-ribofuranosyl)-acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;100%
(S)-Citronellal
5949-05-3

(S)-Citronellal

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

(3S)-1-cyano-3,7-dimethyloct-6-en-1-yl diethylphosphate

(3S)-1-cyano-3,7-dimethyloct-6-en-1-yl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;100%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

lilial
80-54-6

lilial

3-[4-(tert-butyl)phenyl]-1-cyano-2-methylpropyl diethylphosphate

3-[4-(tert-butyl)phenyl]-1-cyano-2-methylpropyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;100%
Diphenylacetaldehyde
947-91-1

Diphenylacetaldehyde

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

1-cyano-2,2-diphenylethyl diethylphosphate

1-cyano-2,2-diphenylethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;100%
2-(allyloxy)benzaldehyde
28752-82-1

2-(allyloxy)benzaldehyde

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

[2-(allyloxy)phenyl]cyanomethyl diethylphosphate

[2-(allyloxy)phenyl]cyanomethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;100%
benzophenone
119-61-9

benzophenone

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

cyanodiphenylmethyl diethylphosphate
88156-52-9

cyanodiphenylmethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
In tetrahydrofuran Ambient temperature;
In tetrahydrofuran for 0.0833333h; Ambient temperature; Yield given;
3,7-dimethyl-2,6-octadienal
141-27-5

3,7-dimethyl-2,6-octadienal

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

(E)-1-cyano-3,7-dimethylocta-2,6-dien-1-yl diethylphosphate

(E)-1-cyano-3,7-dimethylocta-2,6-dien-1-yl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
In tetrahydrofuran Ambient temperature;
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

1-(4-isobutyl-phenyl)-ethanone
38861-78-8

1-(4-isobutyl-phenyl)-ethanone

lithium cyanide
2408-36-8

lithium cyanide

diethyl 1-cyano-1-(4-isobutylphenyl)ethylphosphate
96824-27-0

diethyl 1-cyano-1-(4-isobutylphenyl)ethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
In tetrahydrofuran Ambient temperature;94%
In tetrahydrofuran Ambient temperature;
lithium cyanide
2408-36-8

lithium cyanide

4,5-Bis-(3,4-dimethoxy-phenyl)-2-vinyl-pyridine
184221-01-0

4,5-Bis-(3,4-dimethoxy-phenyl)-2-vinyl-pyridine

3-[4,5-Bis-(3,4-dimethoxy-phenyl)-pyridin-2-yl]-propionitrile
184221-05-4

3-[4,5-Bis-(3,4-dimethoxy-phenyl)-pyridin-2-yl]-propionitrile

Conditions
ConditionsYield
With acetic acid In N,N-dimethyl-formamide at 140℃; for 18h;99%
lithium cyanide
2408-36-8

lithium cyanide

Acetic acid (3aS,4R,6S,7R,7aR)-4-acetoxymethyl-6-methoxy-2,2-dioxo-tetrahydro-2λ6-[1,3,2]dioxathiolo[4,5-c]pyran-7-yl ester
190194-38-8

Acetic acid (3aS,4R,6S,7R,7aR)-4-acetoxymethyl-6-methoxy-2,2-dioxo-tetrahydro-2λ6-[1,3,2]dioxathiolo[4,5-c]pyran-7-yl ester

C9H13O9S(1-)*Li(1+)

C9H13O9S(1-)*Li(1+)

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 20h; Ambient temperature;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

para-methylacetophenone
122-00-9

para-methylacetophenone

1-cyano-1-(p-tolyl)ethyl diethylphosphate

1-cyano-1-(p-tolyl)ethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

caprophenone
942-92-7

caprophenone

lithium cyanide
2408-36-8

lithium cyanide

1-cyano-1-phenylhexyl diethylphosphate

1-cyano-1-phenylhexyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

4-cyanophenyl methyl ketone
1443-80-7

4-cyanophenyl methyl ketone

lithium cyanide
2408-36-8

lithium cyanide

1-cyano-1-(4-cyanophenyl)ethyl diethylphosphate

1-cyano-1-(4-cyanophenyl)ethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

1-(4-trifluoromethylphenyl)ethanone
709-63-7

1-(4-trifluoromethylphenyl)ethanone

lithium cyanide
2408-36-8

lithium cyanide

1-cyano-1-(4-(trifluoromethyl)phenyl)ethyl diethyl phosphate
1469462-84-7

1-cyano-1-(4-(trifluoromethyl)phenyl)ethyl diethyl phosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

3-Nitroacetophenone
121-89-1

3-Nitroacetophenone

1-cyano-1-(3-nitrophenyl)ethyl diethyl phosphate
1469462-86-9

1-cyano-1-(3-nitrophenyl)ethyl diethyl phosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
1-[3-(2-methoxy-ethoxymethoxy)-phenyl]-ethanone

1-[3-(2-methoxy-ethoxymethoxy)-phenyl]-ethanone

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

1-cyano-1-{3-[(2-methoxyethoxy)methoxy]phenyl}ethyl diethylphosphate

1-cyano-1-{3-[(2-methoxyethoxy)methoxy]phenyl}ethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
2-acetylnitrobenzene
577-59-3

2-acetylnitrobenzene

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

1-cyano-1-(2-nitrophenyl)ethyl diethylphosphate

1-cyano-1-(2-nitrophenyl)ethyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

ethyl 3-oxo-3-phenylpropionate
94-02-0

ethyl 3-oxo-3-phenylpropionate

ethyl 3-cyano-3-[(diethoxyphosphoryl)oxy]-3-phenylpropanoate

ethyl 3-cyano-3-[(diethoxyphosphoryl)oxy]-3-phenylpropanoate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

2-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)acetaldehyde
1346144-27-1

2-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)acetaldehyde

lithium cyanide
2408-36-8

lithium cyanide

2-diethylphosphonooxy-3-(2,3,5-tri-O-benzyl-β-ribofuranosyl)-propionitrile

2-diethylphosphonooxy-3-(2,3,5-tri-O-benzyl-β-ribofuranosyl)-propionitrile

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
cis-3,7-dimethyl-2,6-octadienal
106-26-3

cis-3,7-dimethyl-2,6-octadienal

diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

(Z)-1-cyano-3,7-dimethylocta-2,6-dien-1-yl diethylphosphate

(Z)-1-cyano-3,7-dimethylocta-2,6-dien-1-yl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;99%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

cyclododecanone
830-13-7

cyclododecanone

1-cyanocyclododecyl diethylphosphate
88151-69-3

1-cyanocyclododecyl diethylphosphate

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.0833333h;99%
2H-benzo[d]1,3-dioxolane-4-carbaldehyde
7797-83-3

2H-benzo[d]1,3-dioxolane-4-carbaldehyde

lithium cyanide
2408-36-8

lithium cyanide

tert-butyldimethylsilyl chloride
18162-48-6

tert-butyldimethylsilyl chloride

Benzo[1,3]dioxol-5-yl-(tert-butyl-dimethyl-silanyloxy)-acetonitrile
101707-95-3

Benzo[1,3]dioxol-5-yl-(tert-butyl-dimethyl-silanyloxy)-acetonitrile

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Ambient temperature;98%
diethyl cyanophosphonate
2942-58-7

diethyl cyanophosphonate

lithium cyanide
2408-36-8

lithium cyanide

benzaldehyde
100-52-7

benzaldehyde

phosphoric acid (phenyl)(cyano)methyl ester diethyl ester
20435-05-6

phosphoric acid (phenyl)(cyano)methyl ester diethyl ester

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 0.5h;98%
In tetrahydrofuran Ambient temperature;
In tetrahydrofuran for 0.0833333h; Ambient temperature; Yield given;

2408-36-8Relevant articles and documents

Kafafi, Zakya A.,Hauge, Robert H.,Margrave, John L.

, p. 167 - 170 (1983)

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