88292-44-8

Upstream product

• 88292-41-5 2-Oxopropansaeure-<(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)cyclohexyl>ester 
• 10487-92-0 d,l-O-Acetylatrolactinsaeure 
• 65253-04-5 (-)-8-phenylmenthol 
• 75-16-1 methylmagnesium bromide 
• 88002-15-7 Phenylglyoxylsaeure-<(1R,2S,5R)-5-methyl-2-(1-methyl-1-phenylethyl)-1-cyclohexyl>ester 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 138291-09-5 8-Phenylmenthyl (S)-2-phenylpropionate 
• 138291-10-8 (-)-8-Phenylmenthyl (R)-2-phenylpropionate 
• 138291-14-2 2-Methyl-2-phenyl-pent-4-enoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 1123-85-9 (+)-(R)-2-phenylpropanol 
• 37778-99-7 (S)-2-phenyl-1-propanol 
• 2406-22-6 (2S)-2-phenylpropane-1,2-diol 

Relevant academic research and scientific papers

Asymmetric syntheses with a new optically active perhydronaphthalene based chiral auxiliary

(1R,4aS,8S,8aS)-8-(5'-Methoxy-2'-methylphenyl)-8-methyldecahydro-1-nap hthalenol 3a is a highly efficient chiral auxiliary in the Diels-Alder addition of its acrylate ester 5 and in the DIBAL-H and Grignard reactions of its phenylglyoxylate ester 7.

Asymmetric Induction. Reduction, Nucleophilic Addition to, and Ene Reactions of Chiral α-Ketoesters

Ketoesters of 8-phenylmenthol undergo reduction with potassium tri-isopropoxyborohydride, addition of Grignard reagents, and ene reactions with asymmetric induction levels of 90percent and above.