88408-99-5

Upstream product

• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 157733-10-3 (S)-3-Methyl-4-phenylsulfanyl-butyronitrile 
• 882-33-7 diphenyldisulfane 
• 94807-93-9 (S)-3-methyl-4-phenylthio-1-butanol 
• 121783-48-0 (S)-2-methyl-3-(phenylsulfanyl)propanoic acid methyl ester 
• 121783-49-1 (S)-(+)-2-methyl-3-(phenylthio)propan-1-ol 
• 862387-31-3 (S)-4-(tert-Butyl-dimethyl-silanyloxy)-3-methyl-butyric acid 
• 77220-86-1 (S)-4-Hydroxy-3-methyl-butyric acid 
• 188692-78-6 (3S)-4-(tert-butyldimethylsilanyloxy)-3-methylbutyronitrile 
• 156592-93-7 (3S)-4-<(tert-butyldimethylsilyl)oxy>-3-methylbutanol 
• 188692-77-5 (3S)-4-<(1-ethoxyethyl)oxy>-3-methylbutanenitrile 

Downstream Products

• 66261-34-5 (2S,6R)-8-(benzyloxy)-2,6-dimethyloctanol 
• 156592-96-0 (2S,6S)-8-(benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-2,6-dimethyloctane 
• 156593-01-0 1-O-benzyl-2,3-bis-O-<(3R,7R,11S,15S)-16-<(tert-butyldimethylsilyl)oxy>-3,7,11,15-tetramethylhexadecanyl>-sn-glycerol 
• 156593-03-2 (2S,6S,10R,14R)-16-[(S)-2-Benzyloxy-1-((3R,7R,11S,15S)-3,7,11,15-tetramethyl-16-oxo-hexadecyloxymethyl)-ethoxy]-2,6,10,14-tetramethyl-hexadecanal 
• 156593-02-1 1-O-benzyl-2,3-bis-O-<(3R,7R,11S,15S)-16-hydroxy-3,7,11,15-tetramethylhexadecanyl>-sn-glycerol 
• 188692-83-3 (2S,6R,10S,14R)-16-(benzyloxy)-1-<(tert-butyldimethylsilyl)oxy>-2,6,10,14-tetramethyl-8-(phenylsulfonyl)hexadecane 
• 156592-97-1 (2S,6R)-8-(benzyloxy)-1-(phenylsulfonyl)-2,6-dimethyloctane 
• 219654-16-7 [(2R,3R)-3-((E)-(2R,7S)-9-Benzyloxy-2,6,7-trimethyl-4-methylene-non-5-enyl)-oxiranyl]-methanol 
• 1025839-70-6 (E)-(3S,8S)-4-Benzenesulfonyl-10-benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-3,7,8-trimethyl-dec-6-en-5-ol 
• 219654-13-4 (E)-(3S,8S)-4-Benzenesulfonyl-10-benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-3,7,8-trimethyl-dec-6-en-5-one 
• 219654-17-8 (E)-(3S,8S)-10-Benzyloxy-1-(tert-butyl-diphenyl-silanyloxy)-3,7,8-trimethyl-dec-6-en-5-one 
• 219654-14-5 ((E)-(3R,8S)-10-Benzyloxy-3,7,8-trimethyl-5-methylene-dec-6-enyloxy)-tert-butyl-diphenyl-silane 
• 219654-09-8 ((S)-4-Benzenesulfonyl-3-methyl-butoxy)-tert-butyl-diphenyl-silane 
• 219654-15-6 (2E,8E)-(5S,10S)-12-Benzyloxy-5,9,10-trimethyl-7-methylene-dodeca-2,8-dien-1-ol 

Relevant academic research and scientific papers

Synthetic studies toward potent cytotoxic agents amphidinolides: Synthesis of the C1-C18 moiety of amphidinolides G, H and L

Stereoselective synthesis of the (8S, 9S, 11R, 16S)-C1-C18 segment 1 of amphidinolides G, H and L, bearing the unique trisubstituted 's-cis-1,3- diene' moiety (C(28(29))=C13-C14=C15), has been achieved for the first time following a highly efficient convergent strategy.

Total synthesis of archaeal 36-membered macrocyclic diether lipid

Total synthesis of archaeal 36-membered macrocyclic diether lipid 2 is reported. The synthesis is based upon stereoselective preparation of functionalized isoprenoid chains, ether-linkage formation between the isoprenoid chains with a glycerol derivative,

Convergent synthesis of a key intermediate for hypocholesterolemic agent 1233A, starting from methyl 3-hydroxy-2-methylpropanoate and asymmetrized bis(hydroxymethyl)acetaldehyde (BHYMA*)

Compound 2, which is a known intermediate for the total synthesis of hypocholesterolemic agent 1233A 1, has been synthesized in good overall yield through a convergent approach, employing 3-hydroxy-2-methylpropanoate 6 and BHYMA* 5 as chiral building bloc

The First Synthesis of an Archaebacterial 36-Membered Macrocyclic Diether Lipid

The archaebacterial macrocyclic diether lipid featuring of 36-membered ring is synthesized by the McMurry coupling as a key step.