889-37-2

Basic information

• Product Name: N-(4-Dimethylaminobenzylidene)aniline
• Synonyms: N-(4-Dimethylaminobenzylidene)aniline
• CAS NO: 889-37-2
• Molecular Formula: C₁₅H₁₆N₂
• Molecular Weight: 0
• Mol File: 889-37-2.mol
• Article Data: 28

Chemical Properties

• Boiling Point: 363.8°C at 760 mmHg
• Flash Point: 173.8°C
• Appearance: /
• Density: 0.97g/cm³
• Vapor Pressure: 1.76E-05mmHg at 25°C
• Refractive Index: 1.547
• CAS DataBase Reference: N-(4-Dimethylaminobenzylidene)aniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-Dimethylaminobenzylidene)aniline(889-37-2)
• EPA Substance Registry System: N-(4-Dimethylaminobenzylidene)aniline(889-37-2)

Safety Data

• Hazardous Substances Data: 889-37-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H16N2/c1-17(2)15-10-8-13(9-11-15)12-16-14-6-4-3-5-7-14/h3-12H,1-2H3/b16-12+

Upstream product

• 62-53-3 aniline 
• 1703-46-4 N,N-dimethyl-4-hydroxymethylaniline 
• 3526-44-1 N-(4-dimethylaminobenzyl)aniline 
• 33708-54-2 triphenylarsenazophenyl 
• 100-10-7 4-dimethylamino-benzaldehyde 
• 40339-45-5 N,N-dimethyl-4-((Z)-phenylimino-methyl)-aniline 
• 63756-72-9 2-(4-(dimethylamino)phenyl)-2-oxoacetic acid 
• 3435-56-1 diethyl p-(N,N'-dimethylamino)-benzylidenemalonate 
• 60-29-7 diethyl ether 
• 57806-78-7 p-dimethylamino-1-(dichloromethyl)benzene 
• 103-71-9 phenyl isocyanate 
• 71-43-2 benzene 
• 157119-18-1 (4-dimethylamino-phenyl)-oxoacetyl chloride 

Downstream Products

• 103269-75-6 4-(4-dimethylamino-phenyl)-1,3,3-triphenyl-azetidin-2-one 
• 3915-61-5 2-[4-(dimethylamino)styryl]-1-methylquinolinium iodide 
• 536-17-4 5-(4-dimethylaminobenzylidene)rhodanine 
• 57270-81-2 5-(4-dimethylamino-benzylidene)-1,3-dimethyl-pyrimidine-2,4,6-trione 
• 79788-51-5 5-[(4-Dimethylamino-phenyl)-phenylamino-methyl]-3-phenyl-2-thioxo-thiazolidin-4-one 
• 93726-09-1 N-<4-Dimethylamino-benzyliden>-N'-<2-Methylamino-benzoyl>-hydrazin 
• 95822-45-0 2-{[1-(4-Dimethylamino-phenyl)-meth-(E)-ylidene]-amino}-benzoic acid [1-(4-dimethylamino-phenyl)-meth-(E)-ylidene]-hydrazide 
• 857535-08-1 benzoic acid-[N-(4-dimethylamino-benzyl)-anilide] 
• 65321-94-0 2-(4-dimethylamino-styryl)-3-methyl-4-[4-(triphenyl-λ⁵-phosphanylideneamino)-phenyl]-thiazolium; iodide 
• 2562-71-2 2-(4-dimethylaminophenyl)-1H-benzimidazole 
• 1753-47-5 5-(4-dimethylaminobenzylidene)barbituric acid 
• 15795-57-0 5-(4-N,N-dimethylaminobenzylidene)-2,2-dimethyl-1,3-dioxane-4,6-dione 

Relevant articles and documents

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Iron-catalyzed hydrosilylation of imines to amines using a well-defined iron complex is reported. This method employs relatively mild conditions, by reaction of imine, (EtO)3SiH in a 1 : 2 ratio in the presence of 1 mol% precatalyst ([BIAN]Fe(η6-toluene), 3, BIAN = bis(2,6-diisopropylaniline)acenaphthene) at 70 °C. A broad scope of imines was readily converted into the corresponding secondary amines without the need for precatalyst activators.