89366-20-1Relevant articles and documents
Remote stereocontrol in reactions between 4- and 5-alkoxyalk-2- enylstannanes and 1-alkoxycarbonylimines and analogues: Stereoselective approaches to novel α-amino acids
Hallett, David J.,Tanikkul, Nongluk,Thomas, Eric J.
experimental part, p. 6130 - 6158 (2012/09/05)
Reactions of the allyltin trichloride 45 generated from (4S)-4-benzyloxypent-2-enyl(tributyl)stannane 1 with imines prepared from glyoxylates proceed with useful levels of 1,5-stereocontrol in favour of (4E)-2,6-anti-2-(alkylamino)-6-benzyloxyhept-4-enoat
Sulfonimines as bleach catalysts
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, (2008/06/13)
Novel bleach catalysts, a method for bleaching substrates using these catalysts and detergent compositions containing the catalysts are reported. The catalysts are sulfonimines. Substrates such as fabrics may be bleached in an aqueous solution containing
The Products of an Imino Diels-Alder Reaction with 2-Trimethylsilyloxycyclohexadiene: Synthesis, X-Ray Crystal Structures, and Mechanistic Implications
Birkinshaw, Timothy N.,Tabor, Alethea B.,Holmes, Andrew B.,Kaye, Perry,Mayne, Peter M.,Raithby, Paul R.
, p. 1599 - 1601 (2007/10/02)
The reaction of the N-tosyl imino-ester (1) with 2-trimethylsilyloxycyclohexadiene (2) followed by acidic work-up shows a divergence in pathways: at low temperature in polar solvents the cyclohexenones (5) and (6) (X-ray) are favoured, whereas at higher temperatures the bicyclic ketones (3) and (4) (X-ray) are the predominant products.
