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90-26-6

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90-26-6 Usage

Uses

Different sources of media describe the Uses of 90-26-6 differently. You can refer to the following data:
1. antihypercholesterolemia
2. α-Phenyl-α-ethylacetamide acts as a hypolipaemic agent used in the treatment of high levels of cholesterol.

Hazard

Moderately toxic by ingestion.

Safety Profile

A poison by intravenous route.Moderately toxic by ingestion. When heated todecomposition it emits toxic vapors of NOx.

Purification Methods

Crystallise the amide from H2O, EtOH, Et2O/pet ether or *C6H6. [Beilstein 9 I 212, 9 II 356, 9 III 2466.]

Check Digit Verification of cas no

The CAS Registry Mumber 90-26-6 includes 5 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 2 digits, 9 and 0 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 90-26:
(4*9)+(3*0)+(2*2)+(1*6)=46
46 % 10 = 6
So 90-26-6 is a valid CAS Registry Number.
InChI:InChI=1/C10H13NO/c1-2-9(10(11)12)8-6-4-3-5-7-8/h3-7,9H,2H2,1H3,(H2,11,12)/t9-/m0/s1

90-26-6 Well-known Company Product Price

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  • Alfa Aesar

  • (A18501)  2-Phenylbutyramide, 97%   

  • 90-26-6

  • 100g

  • 607.0CNY

  • Detail
  • Alfa Aesar

  • (A18501)  2-Phenylbutyramide, 97%   

  • 90-26-6

  • 500g

  • 2215.0CNY

  • Detail
  • USP

  • (1562033)  Primidone Related Compound C  United States Pharmacopeia (USP) Reference Standard

  • 90-26-6

  • 1562033-20MG

  • 14,578.20CNY

  • Detail

90-26-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Phenylbutyramide

1.2 Other means of identification

Product number -
Other names Benzeneacetamide, α-ethyl-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:90-26-6 SDS

90-26-6Relevant articles and documents

Eberhardt et al.

, p. 4365,4366,4367 (1974)

Base-controlled chemoselectivity: direct coupling of alcohols and acetonitriles to synthesise α-alkylated arylacetonitriles or acetamides

Bai, Liang,Ge, Min-Tong,Li, Chen,Qiu, Yuan-Rui,Wang, Ying,Xia, Ai-Bao,Xu, Dan-Qian

supporting information, p. 15200 - 15204 (2021/09/06)

We achieved chemoselective synthesis of α-alkylated arylacetonitriles and acetamides by combining Ir complex-catalysed direct coupling of alcohols and nitriles by a simple adjustment of the base. Methanol and ethanol performed well as the alkylating reagents. This method of acetonitrile alkylation provided a novel approach for carbon chain extension.

Lithium/DTBB-induced reduction of N-alkoxyamides and acyl azides

Yus, Miguel,Radivoy, Gabriel,Alonso, Francisco

, p. 914 - 918 (2007/10/03)

A series of N-alkoxyamides and N-methoxy-N-methylamides (Weinreb amides) have been subjected to dealkoxylation by reductive cleavage of the N-O bond with lithium powder and a catalytic amount of DTBB (10 mol%) at room temperature, leading to the corresponding amides. When the reaction is performed under reflux conditions, the corresponding alkanes, resulting from a formal deaminocarbonylation process, are obtained. This methodology applied to acyl azides furnished the corresponding primary amides.

Stereoselective Hydrolysis of Nitriles and Amides Under Mild Conditions Using a Whole Cell Catalyst

Beard, Timothy,Cohen, Mark A.,Parratt, Julian S.,Turner, Nicholas J.,Crosby, John,Moilliet, Jock

, p. 1085 - 1104 (2007/10/02)

An immobilised whole cell Rhodococcus sp. (SP 361) has been shown to be an effective catalyst for the stereoselective hydrolysis of both racemic and prochiral nitrile containing compounds. 2-Alkyl-arylacetonitriles 6a-8a were hydrolysed to (S)-acids and (R)-amides whereas the closely related substrate 9a gave the (R)-acid.A series of prochiral dinitriles 10a-13a were hydrolysed to the corresponding (S)-acids with e.e.'s 22-84percent.Models to account for the stereoselectivity of the enzymic hydrolyses have been proposed.

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