90108-26-2

Basic information

• Product Name: 4-Decynal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-
• CAS NO: 90108-26-2
• Molecular Formula: C26H34O2Si
• Molecular Weight: 406.64
• Mol File: 90108-26-2.mol

Chemical Properties

• CAS DataBase Reference: 4-Decynal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Decynal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-(90108-26-2)
• EPA Substance Registry System: 4-Decynal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (R)-(90108-26-2)

Safety Data

• Hazardous Substances Data: 90108-26-2(Hazardous Substances Data)

Upstream product

• 90108-30-8 methyl 5(S)-(tert-butyldiphenylsiloxy)-10-hydroxydec-8-en-6-ynoate 
• 90108-31-9 (E)-(S)-10-Bromo-5-(tert-butyl-diphenyl-silanyloxy)-dec-8-en-6-ynoic acid methyl ester 
• 148519-84-0 (2R)-2-<(tert-butyldiphenylsilyl)oxy>-4-decynyl 4-nitrobenzoate 
• 148519-83-9 (2R)-2-hydroxy-4-decynyl 4-nitrobenzoate 
• 90108-29-5 (5S)-5-t-butyl diphenyl silyloxy-hept-6-ynoic acid, methyl ester 
• 628-71-7 1-Heptyne 
• 119414-22-1 9(R),12(R)-bis<(tert-butyldiphenylsilyl)oxy>-10(S),11(S)-O-(1-methylethylidene)-6,14-icosadiyne-10,11-diol 
• 178060-96-3 (9R,10S,11S,12R)-9,12-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-6,14-diyne-10,11-diol 
• 90108-33-1 (2R)-2-<(tert-butyldiphenylsilyl)oxy>-4-decyn-1-ol 

Downstream Products

• 71160-24-2 Leukotriene B 
• 83058-42-8 Methyl (5S,6Z,8E,10E,12R,14Z)-5,12-Dihydroxyeicosa-6,8,10,14-tetraenoate 
• 90108-36-4 (5S,6Z,8E,10E,12R,14Z)-methyl 5,12-bis<(tert-butyldiphenylsilyl)oxy>-6,8,10,14-eicosatetraenoate 
• 90108-34-2 (5S,8E,10E,12R)-methyl 5,12-bis<(tert-butyldiphenylsilyl)oxy>-8,10-eicosadiene-6,14-diynoate 
• 90132-08-4 (8E,10E,14Z)-(5S,12R)-5,12-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-8,10,14-trien-6-ynoic acid methyl ester 
• 116012-53-4 (5Z,8Z,10E)-(R)-12-(tert-Butyl-diphenyl-silanyloxy)-icosa-5,8,10-trien-14-ynoic acid methyl ester 
• 82337-46-0 (R)-12-HETE 
• 124629-69-2 7(R)-(tert-butyldiphenylsilyloxy) pentadeca-3(E),5(E)-diene-1,9-diyne 
• 178060-99-6 [(R)-1-((1E,3E)-5-Bromo-penta-1,3-dienyl)-non-3-ynyloxy]-tert-butyl-diphenyl-silane 
• 178060-98-5 (2E,4E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-2,4-dien-8-yn-1-ol 
• 116012-52-3 (2E,4R)-4-<(tert-butyldiphenylsilyl)oxy>-2-dodecen-6-ynal 
• 178060-97-4 (2E,4E)-(R)-6-(tert-Butyl-diphenyl-silanyloxy)-tetradeca-2,4-dien-8-ynal 

Relevant articles and documents

Synthesis of (2E,4E)-dienals by double formyl-olefination with an arsonium salt and its application in the syntheses of lipoxygenase metabolites of arachidonic acid

A new facile route to (2E,4E)-dienals by a double formyl-olefination with arsonium salts has been developed. By this method and with other arsonium reagents in the key step some lipoxygenase metabolites of arachidonic acid, lipoxin A4 and B4 and leukotriene B4, have been synthesized.

A GENERAL AND STEREOCONTROLLED TOTAL SYNTHESIS OF LEUKOTRIENE B4 AND ANALOGUES

A new, general, and stereocontrolled total synthesis of leukotriene B4 (1) is disclosed.The application of the methodology to the synthesis of several novel analogues of leukotriene B4 is also described.