90108-29-5

Basic information

• Product Name: 6-Heptynoic acid, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (S)-
• CAS NO: 90108-29-5
• Molecular Formula: C24H30O3Si
• Molecular Weight: 394.586
• Mol File: 90108-29-5.mol

Chemical Properties

• CAS DataBase Reference: 6-Heptynoic acid, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Heptynoic acid, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (S)-(90108-29-5)
• EPA Substance Registry System: 6-Heptynoic acid, 5-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, methyl ester, (S)-(90108-29-5)

Safety Data

• Hazardous Substances Data: 90108-29-5(Hazardous Substances Data)

Upstream product

• 90108-28-4 (5S)-5-hydroxy-hept-6-ynoic acid, methyl ester 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 6026-86-4 methyl 4-formylbutanoate 
• 120085-71-4 (S)-5-hydroxy-7-trimethylsilylhept-6-ynoic acid methyl ester 
• 177407-89-5 4-((2R,4S)-4-Methyl-[1,3]dioxan-2-yl)-butyric acid methyl ester 
• 177407-90-8 (S)-5-((S)-3-Hydroxy-1-methyl-propoxy)-7-trimethylsilanyl-hept-6-ynoic acid methyl ester 
• 1501-26-4 methyl 4-(chlorocarbonyl)butyrate 
• 90132-06-2 5-oxo-7-trimethylsilylhept-6-ynoic acid methyl ester 

Downstream Products

• 123206-49-5 methyl (6Z,10E,12E,5S,14R,15S)-5-(tert-butyldiphenylsiloxy)-14,15-bis(tert-butyldimethylsiloxy)-6,10,12-eicosatrien-8-ynoate 
• 123206-48-4 methyl (5S)-7-iodo-5-(tert-butyldiphenylsiloxy)hept-6-enoate 
• 90132-08-4 (8E,10E,14Z)-(5S,12R)-5,12-Bis-(tert-butyl-diphenyl-silanyloxy)-icosa-8,10,14-trien-6-ynoic acid methyl ester 
• 90108-31-9 (E)-(S)-10-Bromo-5-(tert-butyl-diphenyl-silanyloxy)-dec-8-en-6-ynoic acid methyl ester 
• 90108-34-2 (5S,8E,10E,12R)-methyl 5,12-bis<(tert-butyldiphenylsilyl)oxy>-8,10-eicosadiene-6,14-diynoate 
• 90108-36-4 (5S,6Z,8E,10E,12R,14Z)-methyl 5,12-bis<(tert-butyldiphenylsilyl)oxy>-6,8,10,14-eicosatetraenoate 
• 90108-33-1 (2R)-2-<(tert-butyldiphenylsilyl)oxy>-4-decyn-1-ol 
• 90108-25-1 (E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-10-(dimethoxy-phosphoryl)-dec-8-en-6-ynoic acid methyl ester 
• 90108-26-2 (2R)-2-<(tert-butyldiphenylsilyl)oxy>-4-decynal 
• 71160-24-2 Leukotriene B 
• 177407-94-2 (6E,11Z,14Z)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-icosa-6,11,14-trien-8-ynoic acid methyl ester 
• 177407-92-0 (E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-7-iodo-hept-6-enoic acid methyl ester 
• 123206-47-3 methyl (5S)-7-iodo-5-(tert-butyldiphenylsiloxy)hept-6-ynoate 
• 90108-30-8 methyl 5(S)-(tert-butyldiphenylsiloxy)-10-hydroxydec-8-en-6-ynoate 

Relevant articles and documents

An efficient total synthesis of 5-(S)-HETE

A short and convergent synthesis of (5S)-HETE 1a was accomplished by coupling of two easily accessible synthons 2 and 3a.

A GENERAL AND STEREOCONTROLLED TOTAL SYNTHESIS OF LEUKOTRIENE B4 AND ANALOGUES

A new, general, and stereocontrolled total synthesis of leukotriene B4 (1) is disclosed.The application of the methodology to the synthesis of several novel analogues of leukotriene B4 is also described.