91-89-4Relevant academic research and scientific papers
One-step synthesis of alpha-pyrones from acyl chlorides by the Stille reaction.
Thibonnet, Jerome,Abarbri, Mohamed,Parrain, Jean-Luc,Duchene, Alain
, p. 3941 - 3944 (2007/10/03)
Palladium-catalyzed stereoselective annulation of a functional vinylstannane by acyl chlorides gives the corresponding alpha-pyran-2-ones in good yields. This annulation most probably proceeds through a Stille reaction/cyclization sequence.
Lewis Acid-Promoted Disproportionation Reaction of Aromatic Vinyl Ethers and Acetals and Its Application to the Synthesis of Paracotoin
Gong, Young Dae,Tanaka, Hiroko,Iwasawa, Nobuharu,Narasaka, Koichi
, p. 2181 - 2185 (2007/10/03)
Aromatic vinyl ethers and acetals underwent a novel addition-fragmentation reaction affording olefins and esters in the presence of a Lewis acid. This reaction was applied to intramolecular cyclization reaction, giving five or six membered ring compounds in good yields. Paracotoin, an intermediate in the biosynthesis of shikimic acid, was synthesized using this cyclization reaction as the key step.
Synthesis and Reaction of 6-Substituted 3-Methoxycarbonyl-4-methylthio-2H-pyran-2-one Derivatives
Tominaga, Yoshinori,Ushirogochi, Atsuyuki,Matsuda, Yoshiro
, p. 1557 - 1567 (2007/10/02)
Reaction of aryl and styryl methyl ketones 1a-m with dimethyl bis(methylthio)methylenemalonate (2) in the presence of potassium hydroxide in dimethyl sulfoxide gave the corresponding methyl 6-aryl- and 6-styryl-4-methylthio-2-oxo-2H-pyran-3-carboxylates 3
