91028-46-5

Basic information

• Product Name: Carbamic acid, [1-(hydroxymethyl)-2-propenyl]-, phenylmethyl ester, (S)-
• CAS NO: 91028-46-5
• Molecular Formula: C12H15NO3
• Molecular Weight: 221.256
• Mol File: 91028-46-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [1-(hydroxymethyl)-2-propenyl]-, phenylmethyl ester, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [1-(hydroxymethyl)-2-propenyl]-, phenylmethyl ester, (S)-(91028-46-5)
• EPA Substance Registry System: Carbamic acid, [1-(hydroxymethyl)-2-propenyl]-, phenylmethyl ester, (S)-(91028-46-5)

Safety Data

• Hazardous Substances Data: 91028-46-5(Hazardous Substances Data)

Upstream product

• 75266-40-9 N-benzyloxycarbonyl-L-α-vinylglycine methyl ester 
• 186759-45-5 (+/-)-(1-hydroxymethallyl)carbamic acid benzyl ester 
• 31139-36-3 dibenzyl dicarbonate 
• 75266-42-1 (S)-2-<(benzyloxycarbonyl)amino>-3-butenoic acid 
• 501-53-1 benzyl chloroformate 
• 313995-40-3 (2S)-1-hydroxybut-3-en-2-methylpyrrole-2-carboxylate 
• 91028-47-6 (S)-2-<(benzyloxy)carbonyl>amino-3-buten-1-yl acetate 
• 1152-62-1 N-benzyloxycarbonyl-L-methionine 
• 117609-25-3 (S)-(+)-2-amino-1-butanol 

Downstream Products

• 150674-61-6 ((S)-1-Methoxymethoxymethyl-allyl)-carbamic acid benzyl ester 
• 182890-46-6 ((E)-(S)-3-Cyclohex-1-enyl-1-hydroxymethyl-allyl)-carbamic acid benzyl ester 
• 91028-47-6 (S)-2-<(benzyloxy)carbonyl>amino-3-buten-1-yl acetate 
• 182890-45-5 [(E)-(S)-1-(tert-Butyl-diphenyl-silanyloxymethyl)-3-cyclohex-1-enyl-allyl]-carbamic acid benzyl ester 
• 182890-44-4 {(E)-(S)-3-Cyclohex-1-enyl-1-[dimethyl-(1,1,2-trimethyl-propyl)-silanyloxymethyl]-allyl}-carbamic acid benzyl ester 
• 182890-43-3 2,2-Dimethyl-propionic acid (E)-(S)-2-benzyloxycarbonylamino-4-cyclohex-1-enyl-but-3-enyl ester 
• 890649-00-0 benzyl [(1R,2R,3S)-1-(tert-butyldimethylsilanyloxymethyl)-6-(1,3-dioxolan-2-yl)-2,3-dihydroxy-4-oxo-hexyl]carbamate 
• 890649-01-1 benzyl [(E)-(S)-1-(tert-butyldimethylsilanyloxymethyl)-6-(1,3-dioxolan-2-yl)-4-oxo-hex-2-enyl]carbamate 
• 672964-46-4 benzyl (S)-[1-(tert-butyldimethylsilanyloxymethyl)allyl]carbamate 
• 271260-80-1 (S)-3-(benzyloxycarbonyl)-2,2-dimethyl-4-vinyloxazolidine 

Relevant articles and documents

Catalytic enantioselective synthesis of 4-vinyl-2-trichloromethyloxazoline: An access to enantioenriched vinylglycinol surrogate

Cationic Pd(II) catalysts generated from chiral biphenyl diphosphine complexes or from COP-Cl promote enantioselective cyclization of E- and Z-configured allylic bis-trichloroacetimidates to highly enantioenriched 2-trichloromethyl-4-vinyloxazoline. This

An efficient and scalable synthesis of N-(benzyloxycarbonyl)- and N-(methyloxycarbonyl)-(S)-vinylglycinol

An efficient and scalable synthesis of N-(benzyloxycarbonyl)- and N-(methyloxycarbonyl)-(S)-vinylglycinol has been reported starting from the commercially available (l)-methionine. The scale-up preparation consisted of 5 steps and delivered up to 50 g of the desired N-protected β-amino alcohols in 32% and 36% overall yields.

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