91202-39-0

Basic information

• Product Name: 6-oxo-6-p-tolylhexanoic acid methyl ester
• Synonyms: 6-oxo-6-p-tolylhexanoic acid methyl ester
• CAS NO: 91202-39-0
• Molecular Weight: 234.295
• Mol File: 91202-39-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 6-oxo-6-p-tolylhexanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 6-oxo-6-p-tolylhexanoic acid methyl ester(91202-39-0)
• EPA Substance Registry System: 6-oxo-6-p-tolylhexanoic acid methyl ester(91202-39-0)

Safety Data

• Hazardous Substances Data: 91202-39-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 1821-23-4 1-cyclohex-1-enyl-4-methylbenzene 
• 186581-53-3 diazomethane 
• 100847-96-9 5-(p-toluoyl)valeric acid 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 108-88-3 toluene 
• 2035-75-8 adipic anhydride 
• 106-38-7 para-bromotoluene 
• 35444-44-1 methyl adipoyl chloride 

Downstream Products

• 124016-82-6 6-(4-Methyl-3-nitro-phenyl)-heptanoic acid 
• 124016-75-7 6-(3-methoxy-4-methylphenyl)heptanoic acid 
• 124016-83-7 6-(3-Hydroxy-4-methyl-phenyl)-heptanoic acid 
• 124034-05-5 6-(3-Amino-4-methyl-phenyl)-heptanoic acid 
• 124016-77-9 6-(4-methylphenyl)heptanoic acid 
• 91202-35-6 6-{4-[(E)-2-(4-Butyl-phenyl)-vinyl]-phenyl}-hexanoic acid 
• 91202-44-7 6-{4-[(E)-2-(4-Butyl-phenyl)-vinyl]-phenyl}-6-oxo-hexanoic acid methyl ester 
• 91202-47-0 6-{4-[(E)-2-(4-Butyl-phenyl)-vinyl]-phenyl}-hexanoic acid methyl ester 
• 91202-41-4 6-(4-Bromomethyl-phenyl)-6-oxo-hexanoic acid methyl ester 
• 124016-76-8 6-hydroxy-6-(4-methylbenzoyl)heptanoic acid 

Relevant articles and documents

Solid-supported cross-metathesis and a formal alkane metathesis for the generation of biologically relevant molecules

Solid-phase synthetic strategies toward the generation of libraries of biologically relevant molecules were developed using olefin cross-metathesis as a key step. It is remarkably the formal alkane metathesis based on a one-pot, microwave-assisted, ruthenium-catalyzed cross-metathesis and reduction to obtain Csp3-Csp3 linkages.

Synthesis of 2-hydroxy-3,6,10-trimethylbenzocyclooct-5-ene (isoparvifolin), a sesquiterpenic benzocyclooctene

The synthesis of 2-hydroxy-3,6,10-trimethylbenzocyclooct-5-ene (2) (isoparvifolin), a double bond isomer of the naturally occuring phenolic sesquiterpene (1) (parvifolin) is described.The key intermediate, 6-(3-methoxy-4-methylphenyl)heptanoic acid (3), required for the synthesis of 2 has been made from the keto ester (4) in two ways (4 -> 5 -> 6 -> 7 -> -> 3; 4-> -> 8 -> -> 3).The methoxyaryl heptanoic acid (3) is cyclodehydrated to the benzocyclooctanone (9).Vilsmeier reaction on the corresponding benzocyclooctanol, obtained by NaBH4 reduction of 9 gives the unsaturated aldehyde (10).Two functional group transformations on 10 (CHO -> CH3 and OCH3 -> OH) by standard procedures finally yield isoparvifolin (2).

Hydrophobic-Hydrophylic Interaction in Sodium Dodecyl Sulphate Micelles. Stilbene-Viologen Complex Formation as a Probe of the Micelle Interior

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