91479-17-3Relevant academic research and scientific papers
Intermolecular addition reaction to alkenes of acylmolybdenum complexes generated by oxidative addition of aryl or alkenyl halides with molybdenum(0) carbonyl complexes
Sangu, Kenichiro,Watanabe, Toru,Takaya, Jun,Iwasawa, Nobuharu
, p. 929 - 933 (2008/02/02)
Acylmolybdenum species, generated by oxidative addition of aryl or alkenyl halides with molybdenum(0) carbonyl complex followed by carbon monoxide insertion, added to various kinds of alkenes intermolecularly to give simple addition products in good yields without formation of carbonylative Heck-type products. Georg Thieme Verlag Stuttgart.
Generation of 2-Carboethoxyethylzinc Iodide and 3-Carboethoxypropylzinc Iodide and Their Application to the Synthesis of γ- and δ-Keto Esters
Tamaru, Yoshinao,Ochiai, Hirofumi,Nakamura, Tatsuya,Tsubaki, Kazunori,Yoshida, Zen-ichi
, p. 5559 - 5562 (2007/10/02)
2-Carboethoxyethylzinc iodide and 3-carboethoxypropylzinc iodide are generated by the reaction of the corresponding iodoesters with Zn-Cu couple and utilized for the palladium catalyzed coupling reaction with acid chloride to quantitatively provide gamma- and delta- keto esters, respectively
