92409-15-9

Basic information

• Product Name: 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol
• Synonyms: 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol
• CAS NO: 92409-15-9
• Molecular Formula: C₁₇H₂₀O₅
• Molecular Weight: 304.3377
• Mol File: 92409-15-9.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 500.8±50.0 °C(Predicted)
• Appearance: /
• Density: 1.211±0.06 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Store in freezer, under -20°C
• PKA: 13.38±0.20(Predicted)
• CAS DataBase Reference: 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol(92409-15-9)
• EPA Substance Registry System: 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol(92409-15-9)

Safety Data

• Hazardous Substances Data: 92409-15-9(Hazardous Substances Data)

Usage

General Description

2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol, also known as bisphenol F, is a chemical compound used in the production of polymers and epoxy resins. The compound contains two methoxyphenoxy groups and one methoxyphenyl group attached to a propane-1,3-diol backbone. It is commonly used in the manufacture of thermal paper, protective coatings, and as a hardener in epoxy resins. However, there has been concern about its potential health effects, as bisphenol F is a known endocrine disruptor and has been linked to reproductive and developmental toxicity. Due to these concerns, there has been a push to find safer alternatives to bisphenol F in various industrial applications.

Upstream product

• 227300-29-0 2-(2-methoxyphenoxy)-1-phenylpropane-1,3-diol 
• 50-00-0 formaldehyd 
• 92409-23-9 3-hydroxy-2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propan-1-one 
• 13078-21-2 ethyl 2-(2-methoxyphenoxy)acetate 
• 123-11-5 4-methoxy-benzaldehyde 
• 90-05-1 2-methoxy-phenol 
• 2632-13-5 2-Bromo-4'-methoxyacetophenone 
• 19513-80-5 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethan-1-one 

Downstream Products

• 90-05-1 2-methoxy-phenol 
• 92409-23-9 3-hydroxy-2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)propan-1-one 
• 6437-46-3 1-(2-methoxyphenoxy)propan-2-one 
• 123-11-5 4-methoxy-benzaldehyde 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 121-97-1 4-Methoxypropiophenone 
• 104-45-0 4-n-propylanisole 
• 104-46-1 anethole 
• 1515-95-3 p-ethylanisole 
• 100-09-4 4-methoxybenzoic acid 
• 60036-50-2 2-methoxyphenyl 4-methoxybenzoate 
• 121-98-2 methyl 4-methoxybenzoate 
• 22675-96-3 2-methoxyphenoxy-3',4'-dimethoxyacetophenone 
• 70760-15-5 1-(4'-Methoxyphenyl)-1,3-propanediol 

Relevant articles and documents

Cleavage∕cross-coupling strategy for converting β-O-4 linkage lignin model compounds into high valued benzyl amines via dual C–O bond cleavage

Lignin is the most recalcitrant of the three components of lignocellulosic biomass. The strength and stability of the linkages have long been a great challenge for the degradation and valorization of lignin biomass to obtain bio-fuels and commercial chemicals. Up to now, the selective cleavage of C–O linkages of lignin to afford chemicals contains only C, H and O atoms. Our group has developed a cleavage/cross-coupling strategy for converting 4-O-5 linkage lignin model compounds into high value-added compounds. Herein, we present a palladium-catalyzed cleavage/cross-coupling of the β-O-4 lignin model compounds with amines via dual C–O bond cleavage for the preparation of benzyl amine compounds and phenols.

A multicentre synergistic polyoxometalate-based metal-organic framework for one-step selective oxidative cleavage of β-: O -4 lignin model compounds

A novel mixed-valence polyoxovanadate-based copper-organic framework, [CuI(bbi)]2{[CuI(bbi)]2VIV2VV8O26}·2H2O (NENU-MV-5, bbi = 1,1′-(1,4-butanediyl)bis(imidazole)), was facilely synthesized from routine reagents under mild hydrothermal conditions. Using NENU-MV-5 as a heterogeneous catalyst without any co-catalyst, one-step oxidative cleavage of β-O-4 lignin into phenols and aromatic acids with high catalytic activity and selectivity was realized under an oxygen atmosphere. No obvious decrease in activity was observed after five cycles, which indicates the excellent stability and sustainability of NENU-MV-5. The perfect catalytic performance of NENU-MV-5 can be attributed to the multi-site synergistic effect of the mixed-valence VV-O-VIV sites on polyoxovanadate for the oxidation of β-O-4 alcohol to β-O-4 ketone and the Cu(i) sites on the framework for the rapid cleavage of the Cα-Cβ bond of β-O-4 ketone. This system represented the first co-catalyst-free example for the one-step selective degradation of lignin catalyzed by a well-defined crystalline catalyst with definite composition and structure in a single solvent.

Selective Cα Alcohol Oxidation of Lignin Substrates Featuring a β-O-4 Linkage by a Dinuclear Oxovanadium Catalyst via Two-Electron Redox Processes

Developing highly efficient catalyst systems to transform lignin biomass into value-added chemical feedstocks is imperative for utilizing lignin as renewable alternatives to fossil fuels. Recently, the pre-activated strategy involving the selective oxidat