928-01-8Relevant articles and documents
Method for preparing 1, 2, 4-butantriol through catalytic hydrogenation
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Paragraph 0016-0028, (2020/05/30)
The invention discloses a method for preparing 1, 2, 4-butantriol by catalytic hydrogenation, and the method comprises the following steps: (1) uniformly mixing dimethyl malate and n-propylamine in acertain proportion, reacting at the condensation reflux temperature of the n-propylamine, and cooling to room temperature; removing volatile components through vacuum evaporation; recrystallizing, purifying and the like to obtain corresponding malate diamide; and (2) uniformly mixing the corresponding malate diamide obtained in the step (1) and tetrahydrofuran, carrying out a hydrogenation reaction with hydrogen in the presence of a catalyst at a reaction temperature of 120-200 DEG C under an initial reaction pressure of 5-10 MPa for 10-14 h, and collecting the target product 1, 2, 4-butantriol in the reaction product. The method provided by the invention has the advantages of low cost, mild conditions, simple processing and no pollution to the environment, the reaction yield can reach 85%or above, and the method is easy for industrial implementation.
Butenoic acid derivatives and use as herbicides
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, (2008/06/13)
A butenoic acid derivative of the formula: STR1 which is useful as a herbicide.
Amino alcohols
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, (2008/06/13)
Compounds of the formulas EQU1 including particular derivatives thereof, are provided. The subject compositions have utility in a wide variety of applications and their use as corrosion inhibitors for metals is exemplary.