93420-35-0Relevant academic research and scientific papers
Facile synthesis of 3-(p-alkoxyphenyl)-3-methyl-2-butanones
Gopalakrishnan,Anandhi
, p. 2521 - 2528 (1995)
A novel procedure for the preparation of 3-(p-hydroxyphenyl)-3-methyl-2-butanone, in excellent yield, is described via a simple AlCl3 catalysed rearrangement of p-ethoxy-pivalophenone. Various 3-(p-alkoxyphenyl)-3-methyl-2-butanones have been s
Intramolecular electron transfer initiated cation and radical formation through carbon-carbon bond activation
Wangyang, Tu,Floreancig, Paul E.
, p. 2389 - 2392 (2008/02/05)
Radical cations can be formed in a spatially and temporally controlled manner by appending a sacrificial photooxidant to an easily oxidized substrate, leading to intramolecular electron transfer upon irradiation. The anthraquinone carboxyl group is an effective photooxidant that can promote single electron oxidation from an appended arene. The resulting intermediates undergo a cleavage reaction through carbon-carbon bond activation to provide either cations or radicals that react to form a range of products.
Microwave-assisted Ketone-Ketone rearrangement: An improved synthesis of 3-(4-Alkoxyphenyl)-3-methylbutan-2-ones
Gopalakrishnan, Geetha,Kasinath, Viswanathan,Singh, N. D. Pradeep
, p. 781 - 782 (2007/10/03)
(formula presented) A novel procedure for the preparation of 3-(4-alkoxyphenyl)-3-methylbutan-2-one in excellent yield is described via polymer-supported AlCl3-catalyzed rearrangement of 1-(4-ethoxyphenyl)-2,2-dimehtylpropan-1-one, followed by
Novel Synthesis and Insecticideal Activity of MTI-800, Desfluoro MTI-800 and Their Intermediates
Gopalakrishnan, Geetha,Suresh, G.,Anandhi, S.
, p. 363 - 368 (2007/10/03)
A new route to the synthesis of 2-(4-ethoxyphenyl)-2-methyl-5-(3-phenoxyphenyl)pentane (desfluoro MTI-800) and 2-(4-ethoxyphenyl)-2-methyl-5-(4-fluoro-3-phenoxyphenyl)pentane (MTI-800) and the insecticidal activities of these compounds and some of the synthetic intermediates against the tobacco caterpillar Spodoptera litura (F.) is reported.
