93555-01-2Relevant articles and documents
Cyanosilylation of carbonyl compounds catalyzed by half-sandwich (η6-p-cymene) Ruthenium(II) complexes bearing heterocyclic hydrazone derivatives
Alves, Luis G.,Bharathi, Madheswaran,Indira, Sekar,Martins, Ana M.,Shanmuga Bharathi, Kuppannan,Vinoth, Govindasamy
, (2020/10/02)
A new class of half-sandwich (?6-p-cymene) ruthenium(II) complexes supported by heterocyclic hydrazone derivatives of general formula [Ru(?6-p-cymene)(Cl)(L)] where L represents N’-((1H-pyrrol-2-yl)methylene)furan-2-carbohydrazide (L
Catalyst for cyanosilylation reaction of aldehyde and trimethylsilyl cyanide and preparation method thereof
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Paragraph 0048-0052; 0058-0059, (2021/06/09)
The invention discloses a catalyst for a cyanosilylation reaction of aldehyde and trimethylsilyl cyanide as well as a preparation method and application of the catalyst. The structural formula of the catalyst is shown as a formula 1, and the catalyst is s
Constructing a triangular metallacycle with salen-Al and its application to a catalytic cyanosilylation reaction
Li, Bo,Li, Yang,Qiu, Huayu,Xu, Jun,Yin, Shouchun,Zhang, Jinjin,Zhang, Pengfei,Zhang, Yueyue
supporting information, p. 10399 - 10402 (2021/10/12)
A triangular metallosalen-based metallacycle was constructed in quantitative yield by the self-assembly of a 180° bis(pyridyl)salen-Al complex and a 60° diplatinum(ii) acceptor in a 1?:?1 stoichiometric ratio. This metallacycle was then successfully used to cyanosilylate a wide range of benzaldehydes with trimethylsilyl cyanide.
