93948-20-0

Basic information

• Product Name: BIS-(3-PHENYL-PROPYL)-AMINE
• Synonyms: BIS-(3-PHENYL-PROPYL)-AMINE;DI(3-PHENYL-1-PROPYL)AMINE
• CAS NO: 93948-20-0
• Molecular Formula: C₁₈H₂₃N
• Molecular Weight: 253.38
• Mol File: 93948-20-0.mol
• Article Data: 17

Chemical Properties

• Melting Point: 200-201 °C
• Boiling Point: 245 °C(Press: 35 Torr)
• Appearance: /
• Density: 0.982±0.06 g/cm3(Predicted)
• PKA: 10.47±0.19(Predicted)
• CAS DataBase Reference: BIS-(3-PHENYL-PROPYL)-AMINE(CAS DataBase Reference)
• NIST Chemistry Reference: BIS-(3-PHENYL-PROPYL)-AMINE(93948-20-0)
• EPA Substance Registry System: BIS-(3-PHENYL-PROPYL)-AMINE(93948-20-0)

Safety Data

• Hazardous Substances Data: 93948-20-0(Hazardous Substances Data)

Upstream product

• 104-53-0 3-phenyl-propionaldehyde 
• 2038-57-5 3-Phenylpropan-1-amine 
• 64-17-5 ethanol 
• 13372-81-1 (1E,2Z)-3-phenylacrylaldehyde oxime 
• 1197-50-8 3-phenylpropanal oxime 
• 645-59-0 dihydrocinnamonitrile 
• 110-88-3 1,3,5-Trioxan 
• 100-42-5 styrene 
• 660-68-4 diethyl amine hydrochloride 
• 51-80-9 bis-(dimethylamino)methane 
• 119-64-2 tetralin 
• 60-12-8 2-phenylethanol 
• 141-78-6 ethyl acetate 
• 91-17-8 decalin 

Downstream Products

• 150-59-4 alverine 

Relevant articles and documents

Sequential hydroaminomethylation/Pd-catalyzed hydrogenolysis as an atom efficient route to valuable primary and secondary amines

The facile synthesis of valuable primary and secondary amines is reported using a sequential procedure of hydroaminomethylation and Pd-catalyzed hydrogenolysis. The hydroaminomethylation reaction was catalyzed by a cationic Rh(I) iminopyridyl complex and the N-alkylated benzylamines were produced with high chemoselectivity, albeit as mixtures of linear and branched products. Performing the hydrogenolysis reaction using 10% Pd/C, provided access to valuable primary and secondary amines which have applications in the surfactant, pharmaceutical and polymer industries.

Pd/TiO2-Photocatalyzed Self-Condensation of Primary Amines to Afford Secondary Amines at Ambient Temperature

Symmetric secondary amines were synthesized by the self-condensation of primary amines over a palladium-loaded titanium dioxide (Pd/TiO2) photocatalyst. The reactions afforded a series of secondary amines in moderate to excellent isolated yields at ambient temperature (30 °C, in cyclopentyl methyl ether). Applicability for one-pot pharmaceutical synthesis was demonstrated by a photocatalytic reaction sequence of self-condensation of an amine followed by N-alkylation of the resulting secondary amine with an alcohol.

Conversion of Primary Amines to Symmetrical Secondary and Tertiary Amines using a Co-Rh Heterobimetallic Nanocatalyst

Symmetrical tertiary amines have been efficiently realized from amine and secondary amines via deaminated homocoupling with heterogeneous bimetallic Co2Rh2/C as catalyst (molar ratio Co:Rh=2:2). Unsymmetric secondary anilines were produced from the reaction of anilines with symmetric tertiary amines. The Co2Rh2/C catalyst exhibited very high catalytic activity towards a wide range of amines and could be conveniently recycled ten times without considerable leaching. (Figure presented.).