37542-28-2

Basic information

• Product Name: methyl 2-(4-chlorophenyl)-2-oxoacetate
• Synonyms: methyl 2-(4-chlorophenyl)-2-oxoacetate
• CAS NO: 37542-28-2
• Molecular Weight: 198.606
• Mol File: 37542-28-2.mol
• Article Data: 47

Chemical Properties

• CAS DataBase Reference: methyl 2-(4-chlorophenyl)-2-oxoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-(4-chlorophenyl)-2-oxoacetate(37542-28-2)
• EPA Substance Registry System: methyl 2-(4-chlorophenyl)-2-oxoacetate(37542-28-2)

Safety Data

• Hazardous Substances Data: 37542-28-2(Hazardous Substances Data)

Upstream product

• 32174-34-8 methyl 4-chloromandelate 
• 67-56-1 methanol 
• 27704-37-6 2,2,2-trichloro-1-(4-chlorophenyl)ethanone 
• 52449-43-1 (4-chloro-phenyl)-acetic acid methyl ester 
• 124-41-4 sodium methylate 
• 170166-56-0 2,2-Bis-benzotriazol-1-yl-1-(4-chloro-phenyl)-2-methoxy-ethanone 
• 106-39-8 bromochlorobenzene 
• 72030-76-3 α-oxo-1H-imidazole-1-acetic acid, methyl ester 
• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 331238-93-8 ADC₁₁₃ 
• 7099-88-9 4-chlorophenylglyoxylic acid 
• 18166-02-4 N-trimethylsilylmethylamine 
• 124-38-9 carbon dioxide 
• 75748-10-6 trimethyl-4-chlorobenzoylsilane 

Downstream Products

• 248582-67-4 methyl (Z)-O-methyloximino-2-(4-chloro)phenylacetate 
• 60300-84-7 methyl α-benzyloxyphenylacetate 
• 1086108-75-9 (Z)-methyl 2-(4-chlorophenyl)-2-(4-methoxyphenylimino)acetate 
• 1644539-67-2 methyl (R)-2-(4-chlorophenyl)-5-oxo-3-phenyl-2,5-dihydrofuran-2-carboxylate 
• 1644539-86-5 methyl 2-(4-chlorophenyl)-5-oxo-3-phenyl-2,5-dihydrofuran-2-carboxylate 
• 1644539-71-8 methyl (R)-2-(4-chlorophenyl)-3-(4-methoxyphenyl)-5-oxo-2,5-dihydrofuran-2-carboxylate 
• 1644539-90-1 methyl 2-(4-chlorophenyl)-3-(4-methoxyphenyl)-5-oxo-2,5-dihydrofuran-2-carboxylate 
• 50415-79-7 methyl (E)-2-(4-chlorophenyl)-3-phenylprop-2-enoate 
• 151358-36-0 methyl (Z)-2-(4-chlorophenyl)-3-phenylprop-2-enoate 

Relevant articles and documents

Unraveling two pathways for NHPI-mediated electrocatalytic oxidation reaction

Two pathways for N-hydroxyphthalimide (NHPI)-mediated electrocatalytic oxidation using phenylacetate derivatives as template substrates were first reported for benzylic C[sbnd]H oxidation to oxygenated and non-oxygenated products. DFT calculation indicates that the hydrogen-atom transfer (HAT) process between phthalimido-N-oxyl (PINO) and substrate is a rate-determined step. Aromatic α-keto esters and 2-((1,3-dioxoisoindolin-2-yl)oxy)-2-aryl acetate obtained by cross-coupling between benzylic radical and PINO can be selectively synthesized through controlling the concentration of PINO radical. This method provides a deep understanding for selective weak C[sbnd]H oxidation using NHPI as redox mediator.

Photoinduced Diverse Reactivity of Diazo Compounds with Nitrosoarenes

A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal [2 + 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen source to oxidize an in situ generated carbene intermediate under visible-light irradiation. UV-light-mediated in situ generated ketenes react with nitosoarenes to deliver oxazetidine derivatives. These operationally simple processes exemplify a transition-metal-free and catalyst-free protocol to give structurally diverse α-ketoesters or oxazetidines.

[Fe(bpy)3]2+-based porous organic polymers with boosted photocatalytic activity for recyclable organic transformations

Three rigid metal porous organic polymers (POPs) based on an iron(ii) complex are prepared from the condensation reactions of an octahedral [Fe(bpy)3]2+-cored hexaaldehyde and three rod-like aromatic diamines. The POPs have been studied as the first series of earth-abundant metal complex-connected photocatalysts for heterogeneous visible light-driven oxidation of benzyl halides and enantioselective α-alkylation of aldehydes. Both yields and enantioselectivities of the reactions catalyzed by one of the POPs, which possesses the largest porosity, rival or even surpass those of the reactions homogeneously catalyzed by control [Fe(bpy)3]2+complexes. Moreover, POP catalysts are highly stable and exhibit a considerable activity after recycling 10 times.