94371-04-7

Basic information

• Product Name: methyl 2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside
• Synonyms: methyl 2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside
• CAS NO: 94371-04-7
• Molecular Weight: 252.31
• Mol File: 94371-04-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside(94371-04-7)
• EPA Substance Registry System: methyl 2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside(94371-04-7)

Safety Data

• Hazardous Substances Data: 94371-04-7(Hazardous Substances Data)

Upstream product

• 88096-32-6 methyl 2,4-dideoxy-6-O-benzyl-3-O-allyl-α- and β-D-threo-hexopyranosides 
• 20204-80-2 [(1R,2S,3S,4R,5R)-3-hydroxy-4-(p-tolylsulfonyl)-6,8-dioxabicyclo[3.2.1]oct-2-yl]-4-methylbenzenesulfonic acid 
• 100-39-0 benzyl bromide 
• 88096-28-0 1,6-anhydro-2,4-dideoxy-3-O-allyl-β-D-threo-hexopyranose 
• 88096-30-4 methyl 2,4-dideoxy-3-O-allyl-α and β-D-threo-hexapyranosides 
• 498-07-7 levoglucosan 
• 14241-58-8 (1R,3S,5S)-6,8-dioxabicyclo[3.2.1]octan-3-ol 
• 50880-93-8 levoglucosan tritosylate 
• 94480-26-9 (2S,6S)-tetrahydro-2-methoxy-6-<(phenylmethoxy)methyl>-4H-pyran-4-one 
• 82891-99-4 ethylene ketal of 3-nitropropanal 
• 90344-31-3 (5S)-5-<(4R)-(2,2-dimethyl-1,3-dioxolan-4-yl)>-3-<(1,3-dioxolan-2-yl)methyl>-4,5-dihydroisoxazole 
• 94371-08-1 (5S)-5-(Hydroxymethyl)-3-<(1,3-dioxolan-2-yl)methyl)>-4,5-dihydroisoxazole 
• 94371-07-0 (5S)-5-<(1R)-1,2-dihydroxyethyl>-3-<(1,3-dioxolan-2-yl)methyl>-4,5-dihydroisoxazole 
• 94480-29-2 (2S)-2-benzyloxymethyl-2,3-dihydro-4H-pyran-4-one 

Downstream Products

• 88096-40-6 (4S,6S)-3-diphenyl-t-butylsilyloxy-6-benzoyloxymethyltetrahydropyran-2-one 
• 82415-18-7 (2S,4S,6S,8R,9S)-4-<(tert-butyldiphenylsilyl)oxy>-8,9-dimethyl-1,7-dioxaspiro<5.5>undecane-2-methanol 
• 86030-95-7 methyl 3-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-α-D-erythro-hexopyranoside 
• 86030-94-6 methyl 3-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-β-D-erythro-hexopyranoside 
• 94371-09-2 methyl 3-O-(tert-butyldiphenylsilyl)-2,4-dideoxy-6-O-(phenylmethyl)-α-D-erythro-hexopyranoside 
• 88096-38-2 2,4-dideoxy-3-O-diphenyl-t-butylsilyl-6-O-benzyl-α- and β-D-threo-hexopyranoses 
• 94371-09-2 methyl 2,4-dideoxy-3-O-diphenyl-t-butylsilyl-6-O-benzyl-α- and β-D-threo-hexopyranosides 

Relevant articles and documents

Preparation of a Chiral Lactone from Leavoglucosan; a Key Intermediate for Synthesis of the Spiroacetal Moietes of the Avermectins and Milbemycins

A synthesis of two diprotected (4S,6S)-4-hydroxy-6-hudroxymethyltetrahydropyran-2-ones has been developed from laevoglucosan.Reaction of these lactones with a substituted chiral lithium acetylide followed by hydrogenation and acid-catalysed cyclisation led to formation of the spiroacetal moiety of milbemycin α1 and α3.The acetylene was prepared by resolution of racemic material obtained from reaction of lithium acetylide and cis-butene epoxide.Alternatively a stereocontrolled synthesis was developed from (S)-methyl-3-hydroxy-2-methylpropionate which involved 'chelation controlled' addition of lithium dimethylcuprate to the corresponding tetrahydropyranyloxy aldehyde.

The Chemistry of Spiroacetals. Preparation of a Chiral Disubstituted Lactone Derivative; a Key Intermediate for Synthesis of the Spiroacetal Moieties of the Avermectins and Milbemycins

A synthesis of two diprotected (4S,6S)-4-hydroxy-6-hydroxymethyltetrahydropyran-2-ones has been developed from laevoglucosan; reaction of these lactones with a substituted lithium acetylide derivative followed by hydrogenation and acid catalysed cyclisati