94527-39-6

Basic information

• Product Name: 1-broMo-4-Methoxy-2-(MethoxyMethyl)benzene
• Synonyms: 1-broMo-4-Methoxy-2-(MethoxyMethyl)benzene
• CAS NO: 94527-39-6
• Molecular Formula: C₉H₁₁BrO₂
• Molecular Weight: 231.08644
• Product Categories: alkyl bromide
• Mol File: 94527-39-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 98-100 °C(Press: 0.5 Torr)
• Appearance: /
• Density: 1.369±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-broMo-4-Methoxy-2-(MethoxyMethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-broMo-4-Methoxy-2-(MethoxyMethyl)benzene(94527-39-6)
• EPA Substance Registry System: 1-broMo-4-Methoxy-2-(MethoxyMethyl)benzene(94527-39-6)

Safety Data

• Hazardous Substances Data: 94527-39-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 14, p. 1205, 1984 DOI: 10.1080/00397918408076801

Upstream product

• 66192-25-4 2-bromo-5-methoxybenzyl chloride 
• 124-41-4 sodium methylate 
• 22921-68-2 2-bromo-5-methoxy-benzoic acid 
• 2737-20-4 (2-bromo-5-hydroxybenzene)methanol 
• 74-88-4 methyl iodide 
• 150192-39-5 2-Bromo-5-methoxybenzyl alcohol 
• 19614-12-1 2-bromo-5-methoxybenzyl bromide 

Downstream Products

• 94527-40-9 4-methoxy-2-(methoxymethyl)benzaldehyde 
• 2811-50-9 7-methoxy-4-vinyl-1,2-dihydronaphthalene 
• 681427-55-4 2-(but-3-enyl)-1-ethynyl4-methoxybenzene 
• 842167-69-5 1-(2,2-dibromovinyl)-4-methoxy-2-(methoxymethyl)benzene 
• 842167-53-7 {2-[4-methoxy-2-(methoxymethyl)phenyl]ethynyl}trimethylsilane 
• 842167-54-8 {2-[2-(3-butenyl)-4-methoxyphenyl]ethynyl}trimethylsilane 
• 94527-41-0 2-methoxymethyl-4-methoxybenzyl alcohol 
• 84859-38-1 2-chloromethyl-5-methoxybenzyl methyl ether 
• 84859-40-5 2-cyanomethyl-5-methoxybenzyl methyl ether 
• 1187190-70-0 1,3-dihydro-1,5-dihydroxy-2,1-benzoxaborolane 
• 906673-24-3 AN₂₇₂₈ 
• 1451392-22-5 4-(methoxy)-2-(methoxymethyl)benzeneboronic acid 

Relevant articles and documents

Preparation method of boracic micromolecule

The invention discloses a preparation method of a boracic micromolecule 5-(4-cyanophenoxyl)-1,3-dihydro-1-hydroxy-2,1-benzodioxole. The preparation method includes the steps of (1) subjecting 2-bromine-5-hydroxybenzaldehyde to reduction reaction in solvent with the presence of reducing agents to obtain 2-bromine-5-hydroxybenzyl alcohol; (2) subjecting 2-bromine-5-hydroxybenzyl alcohol and a hydroxyl protection reagent to reaction in solvent with the presence of alkali; (3) subjecting the previous reactant to borate reaction in solvent under an alkaline condition; (4) removing hydroxyl protecting groups from the previous reactant to obtain a benzo[c][1,2]heterocyclopentadiene-1,5(3H)-glycol body; (5) subjecting the previous reactant to reaction in solvent under an alkaline condition to obtain a target object. The preparation method has the advantages of low cost of technological raw materials, easiness in obtaining of the technological raw materials, remarkably improved reaction yield,simplicity in operation, low cost and applicability to industrial production.

AN IMPROVED SYNTHESIS OF 7-METHOXYISOCHROMAN-3-ONE: A SYNTHON FOR GENERATION OF o-QUINODIMETHANES

7-Methoxyisochroman-3-one (8) has been synthesized from 2-bromo-5-methoxybenzyl methyl ether (3) in overall high yield.