951-92-8

Basic information

• Product Name: Benzene, 1-methoxy-4-(phenylsulfinyl)-
• CAS NO: 951-92-8
• Molecular Formula: C13H12O2S
• Molecular Weight: 232.303
• Mol File: 951-92-8.mol
• Article Data: 37

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-(phenylsulfinyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(phenylsulfinyl)-(951-92-8)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(phenylsulfinyl)-(951-92-8)

Safety Data

• Hazardous Substances Data: 951-92-8(Hazardous Substances Data)

Upstream product

• 104-92-7 1-bromo-4-methoxy-benzene 
• 1193-82-4 racemic methyl phenyl sulfoxide 
• 623-12-1 4-chloromethoxybenzene 
• 108-86-1 bromobenzene 
• 3517-99-5 1-methoxy-4-(methylsulfinyl)benzene 
• 66003-76-7 Diphenyliodonium triflate 
• 98-80-6 phenylboronic acid 
• 5720-07-0 4-methoxyphenylboronic acid 
• 4972-29-6 benzenesulphinyl chloride 
• 100-66-3 methoxybenzene 
• 31401-17-9 methyl p-methoxybenzenesulphinate 
• 24388-23-6 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole 
• 670-98-4 methyl benzenesulfinate 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 3112-84-3 4-methoxyphenyl phenyl sulfone 
• 1190852-58-4 C₁₉H₂₂O₂S 
• 1190852-59-5 C₁₉H₂₂O₂S 
• 92507-80-7 (±)-imino(4-methoxyphenyl)(phenyl)-λ⁶-sulfanone 
• 439289-30-2 N-phtalimido-S-(4-methoxyphenyl)-S-phenylsulfoximine 
• 95-57-8 2-monochlorophenol 
• 5633-57-8 1-methoxy-4-(phenylsulfanyl)benzene 
• 106-48-9 4-chloro-phenol 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 1774-36-3 bis(4-methoxyphenyl) sulfoxide 

Relevant articles and documents

Modulation of photochemical oxidation of thioethers to sulfoxides or sulfones using an aromatic ketone as the photocatalyst

We have developed an eco-friendly and chemo-selective photocatalytic synthesis of sulfoxides or sulfones via oxidation of sulfides (thioethers) at ambient temperature using air or O2 as the oxidant. An inexpensive thioxanthone was used as the photocatalyst. Our method offers excellent chemical yields and good functional group tolerance. The hydrogen bonding between hexafluoro-2-propanol (HFIP) and sulfoxides may play an important role in minimizing the over-oxidization of sulfoxides.

Synergistic cooperative effect of CF3SO2Na and bis(2-butoxyethyl)ether towards selective oxygenation of sulfides with molecular oxygen under visible-light irradiation

A safe, practical and eco-friendly method for the switchable synthesis of sulfoxides and sulfones through visible-light-initiated oxygenation of sulfides at ambient temperature under transition-metal-, additives-free and minimal solvent conditions. The synergistic catalytic efforts between CF3SO2Na and 2-butoxyethyl ether represents the key promoting factor for the reaction. This journal is

Room temperature nickel-catalyzed cross-coupling of aryl-boronic acids with thiophenols: Synthesis of diarylsulfides

A NiCl2/2,2′-bipyridine-catalyzed cross-coupling of thiophenols with arylboronic acids has been developed for the synthesis of symmetric and unsymmetric diarylsulfides at room temperature and in air. This methodology is reliable and offers a mild and easy to operate process for the synthesis of arylthioethers, which are essential compounds with applications in the pharmaceutical and agricultural industries. This method avoids the use of expensive transition metals, such as Pd, Ir or Rh, sophisticated ligands and elevated temperatures. It also has a wide substrate scope (55 examples) and provides products in good to excellent yields (72-93%).