95452-95-2

Upstream product

• 95585-63-0 (2S,3S)-1,3-dihydroxy-2-methyl-5-phenyl-4-pentene 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 86838-36-0 (2R,3S)-3-hydroxy-2-methyl-5-phenyl-pent-4-enoic acid ethyl ester 
• 86838-34-8 ethyl 2-methyl-3-oxo-5-phenylpent-4-enoate 

Downstream Products

• 73341-71-6 (-)-oudemanisin A 
• 88644-08-0 (3S,4R,E)-methyl 4-methoxy-3-methyl-6-phenylhex-5-enoate 
• 88088-56-6 (E)-(3S,4R)-4-Methoxy-3-methyl-6-phenyl-hex-5-enoic acid 
• 90664-08-7 (E)-(3S,4S)-2-Formyl-4-methoxy-3-methyl-6-phenyl-hex-5-enoic acid methyl ester 
• 95452-96-3 tert-Butyl-((E)-(2S,3S)-3-methoxy-2-methyl-5-phenyl-pent-4-enyloxy)-dimethyl-silane 

Relevant academic research and scientific papers

THE ABSOLUTE CONFIGURATION OF OUDEMANSIN. TOTAL SYNTHESIS OF (-)-OUDEMANSIN.

(-)-Oudemansin (1) was synthesized from the optically active intermediate 10 obtained by microbiological asymmetric reduction of β-keto ester 3.Oudemansin was found to have the 9S, 10S absolute configuration.