80184-02-7

Basic information

• Product Name: (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol
• Synonyms: (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol
• CAS NO: 80184-02-7
• Molecular Weight: 210.273
• Mol File: 80184-02-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol(80184-02-7)
• EPA Substance Registry System: (2S,3S)-4-(benzyloxy)-3-methyl-1,2-butanediol(80184-02-7)

Safety Data

• Hazardous Substances Data: 80184-02-7(Hazardous Substances Data)

Upstream product

• 88481-59-8 (2S,3S)-3-Methyl-2-(1-methoxy-1-methylethoxy)-1,4-butandiol 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 50460-80-5 (2S,3R)-2-Hydroxy-3-methylbernsteinsaeure-dimethylester 
• 100-39-0 benzyl bromide 
• 88481-58-7 (2S,3R)-3-Methyl-2-(1-methoxy-1-methylethoxy)bernsteinsaeure-diethylester 
• 100-52-7 benzaldehyde 
• 73840-71-8 diethyl (2S,3R)-(+)-2-hydroxy-3-methylsuccinate 
• 95532-11-9 (2S,3S)-1,4-bis(benzyloxy)-3-methylbutan-2-ol 
• 74243-88-2 (βS,4S)-β,2,3-trimethyl-1,3-dioxolane-4-ethanol 
• 74213-64-2 (2S,3S)-erythro-3-methylbutane-1,2,4-triol 
• 97747-37-0 (1S,3S,4S)-3-hydroxymethyl-4-methyl-1-phenyl-1,3-dioxane 
• 95588-29-7 (4S)-4-<(1S)-2-(benzyloxy)-1-methylethyl>-2,2-dimethyl-1,3-dioxolane 
• 78513-15-2 <2R-(2β,3α)>-3-<(phenylmethoxy)methyl>oxiranemethanol 
• 88481-60-1 (4S,5S)-(4-Hydroxymethyl)-5-methyl-2-phenyl-1,3-dioxan 

Downstream Products

• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 81380-10-1 (2S,3S)-4-benzyloxy-1,2-epoxy-3-methylbutane 
• 130740-38-4 (E)-(2S,4S,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undec-7-ene-1,4-diol 
• 130740-38-4 (E)-(2S,4R,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undec-7-ene-1,4-diol 
• 130740-50-0 (R)-2-[(2R,3S)-3-((E)-(1R,2S,5R,6S)-7-Benzyloxy-1-methoxy-5-methoxymethoxy-2,4,6-trimethyl-hept-3-enyl)-oxiranyl]-propan-1-ol 
• 130740-50-0 (R)-2-[3-((E)-(1R,2S,5R,6S)-7-Benzyloxy-1-methoxy-5-methoxymethoxy-2,4,6-trimethyl-hept-3-enyl)-oxiranyl]-propan-1-ol 

Relevant articles and documents

Spirastrellolide E: Synthesis of an advanced C(1)-C(24) southern hemisphere

The synthesis of a C(1)-C(24) advanced southern hemisphere fragment towards the total synthesis of spirastrellolide E has been achieved. Highlights of the route include a highly convergent Type I Anion Relay Chemistry (ARC) tactic for fragment assembly, in conjunction with a directed, regioselective gold-catalyzed alkyne functionalization to generate the central unsaturated [6,6]-spiroketal.

Isomer Selectivity in Stereocontrolled Payne Rearrangement-epoxide Cleavage of 2,3-Epoxy Alcohols in Aprotic Solvents: Application to an Enantioselective Total Synthesis of (+)-exo-Brevicomin

Organo-copper and -cuprate reagents may be used to trap the more reactive epoxy alkoxide isomer in a Lewis acid-catalysed Payne rearrangement process.This methodology has been used as the key step in a five-step enantioselective total synthesis of (+)-exo

Enantioselective total synthesis of ingramycin

An enantioselective total synthesis of the 14-membered macrolide antibiotic ingramycin, 1, is described. In a convergent approach three chiral fragments A,B and C are assembled, the allylic bromide A deriving its chirality from L-serine while the asymmetr