96881-39-9

Basic information

• Product Name: 7-methylwye
• Synonyms: 7-methylwye
• CAS NO: 96881-39-9
• Molecular Formula: C10H11N5O
• Molecular Weight: 217.22724
• Mol File: 96881-39-9.mol

Chemical Properties

• Boiling Point: 635.3°Cat760mmHg
• Flash Point: 338°C
• Appearance: /
• Density: 1.56g/cm³
• Vapor Pressure: 4.8E-16mmHg at 25°C
• Refractive Index: 1.784
• CAS DataBase Reference: 7-methylwye(CAS DataBase Reference)
• NIST Chemistry Reference: 7-methylwye(96881-39-9)
• EPA Substance Registry System: 7-methylwye(96881-39-9)

Safety Data

• Hazardous Substances Data: 96881-39-9(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H11N5O/c1-5-6(2)15-9(16)7-8(12-4-11-7)14(3)10(15)13-5/h4H,1-3H3,(H,11,12)

Upstream product

• 2958-98-7 3-methylguanine 
• 52662-10-9 3,4-Dihydro-4,6-dimethyl-3-β-D-ribofuranosyl-9H-imidazo<1,2-a>purin-9-one 
• 68768-34-3 3,4-Dihydro-4,6-dimethyl-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)-9H-imidazo<1,2-a>purin-9-one 
• 132366-93-9 4,9-Dihydro-4,7-dimethyl-9-oxo-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)-3H-imidazo<1,2-a>purine-6-carboxaldehyde 
• 115436-29-8 3,4-Dihydro-7-(hydroxymethyl)-4,6-dimethyl-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)-9H-imidazo<1,2-a>purin-9-one 
• 115436-28-7 4,9-Dihydro-4,6-dimethyl-9-oxo-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)-3H-imidazo<1,2-a>purine-7-carboxaldehyde 
• 114262-22-5 3,4-Dihydro-4,6,7-trimethyl-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)-9H-imidazo<1,2-a>purin-9-one 
• 65120-81-2 1-benzyl-4,6-dimethyl-1,4-dihydro-imidazo[1,2-a]purin-9-one 
• 65120-78-7 7-benzyl-3-methylguanine 
• 814-75-5 3-bromo-butanone 
• 122775-60-4 1-benzyl-1,4-dihydro-4,6,7-trimethyl-9H-imidazo<1,2-a>purin-9-one 
• 96881-38-8 1-benzyl-1,4-dihydro-7-hydroxymethyl-4,6-dimethyl-9H-imidazo<1,2-a>purin-9-one 
• 108274-04-0 7-methyl-3-β-D-ribofuranosylwye 
• 96881-37-7 1-benzyl-7-formylwye 

Relevant articles and documents

Studies towards the synthesis of the fluorescent bases of phenylalanine transfer ribonucleic acids: synthesis of 7-methylwye isolated from extremely thermophilic archaebacteria.

Acid- or base-catalyzed acylation of 1-benzylwye (7) provided the 7-substituted derivatives 9, 10, and 11 in poor yields. Although the reactions of lithiated 7 with electrophiles gave the 2-substituted derivatives 14, 15, 17, 20, 21, and 22, lithiation of

SYNTHESIS OF (S)-(-)-WYBUTINE, THE FLUORESCENT MINOR BASE FROM YEAST PHENYLALANINE TRANSFER RIBONUCLEIC ACIDS

The Wittig reaction of 1-benzyl-7-formylwye (12) with (R)-ethyl>triphenylphosphonium chlorid (8) followed by successive methylation and reduction gave (-)-wybutine .