Bulletin of the Chemical Society of Japan p. 3030 - 3039 (1994)
Update date:2022-09-26
Topics:
Karatsu, Takashi
Tsuchiya, Masami
Arai, Tatsuo
Sakuragi, Hirochika
Tokumaru, Katsumi
Regarding 2-anthrylethylenes which undergo a photochemical cis-to-trans one-way isomerization, their preparative methods are presented.The isomerization of ArCH=CHPh and ArCH=CH(2-naphthyl) (Ar: 2-anthryl) proceeds through a quantum chain process slightly more efficiently than ArCH=CHtBu.The origin of the high efficiency in the quantum chain process of these ethylenes is discussed.
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