97871-93-7

Basic information

• Product Name: Benzo[b]thiophen-3(2H)-one, 2-[(4-methylphenyl)methylene]-, (Z)-
• CAS NO: 97871-93-7
• Molecular Formula: C16H12OS
• Molecular Weight: 252.337
• Mol File: 97871-93-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzo[b]thiophen-3(2H)-one, 2-[(4-methylphenyl)methylene]-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzo[b]thiophen-3(2H)-one, 2-[(4-methylphenyl)methylene]-, (Z)-(97871-93-7)
• EPA Substance Registry System: Benzo[b]thiophen-3(2H)-one, 2-[(4-methylphenyl)methylene]-, (Z)-(97871-93-7)

Safety Data

• Hazardous Substances Data: 97871-93-7(Hazardous Substances Data)

Upstream product

• 3704-28-7 methyl 2-(methylthio)benzoate 
• 104-87-0 4-methyl-benzaldehyde 
• 3724-10-5 2-(methylthio)benzoic acid 
• 1441-97-0 2'-(methylthio)acetophenone 
• 2142-69-0 2-bromophenyl methyl ketone 
• 147-93-3 Thiosalicylic acid 
• 1531-80-2 2-(benzylthio)benzoic acid 
• 7031-27-8 (phenylthio)acetic acid chloride 
• 103-04-8 (phenylthio)acetic acid 
• 130-03-0 thioindoxyl 

Relevant articles and documents

METHOD FOR SYNTHESIZING THIOAURONES

An embodiment of the present invention is a process for producing 2 - benzoic acid compound by reacting a thiosalicylic acid with a strongly basic substance and a benzylhalide. The 2 - methoxy - N N-methyl -2 - benzamides, which are reacted with N - methoxy - N N-methylcarbamoyl chloride to produce N - methoxy-N-methylbenzamides. The N - methoxy - N N-methyl -2 - (benzocyclohexyl) benzamide is treated with arylethynyl salt to prepare 1 - (2- benzocyclohexyl) phenyl -3 - phenyl -2 - profin -1 . The 1 - (2-) phenyl -3 - phenyl -2 - profin -1 - one is treated with an acid material. Provided is a method for preparing a thiouronone compound.

Competitive cascade cyclization of 2′-tosyloxychalcones: An easy access to thioflavones and thioaurones

A new and efficient approach for the synthesis of thioflavones and thioaurones by competitive cascade cyclization of 2′-tosyloxychalcones has been developed. 2′-Tosyloxychalcones were smoothly converted into thioflavones and thioaurones by incorporation of sulfur atom using elemental sulfur and triethylamine in DMSO with good yields. The advantages of the methodology are the formation of both thioflavones and thioaurones in a single step. Easily accessible substrates, mild reaction conditions and compatibility with a broad range of functional groups make this protocol clean and inexpensive.

Iodine-catalyzed intramolecular oxidative thiolation of vinylic carbon-hydrogen bonds via tandem iodocyclization and dehydroiodination: Construction of 2-methylene-3-thiophenones

A metal-free vinylic carbon-hydrogen bond thiolation has been developed. Under the catalysis of iodine (10 mol%), the cyclization of α-alkenoyl ketene dithioacetals afforded a broad range of polyfunctionalized 2-methylene-3-thiophenones in good selectivity with moderate to excellent yields via tandem iodocyclization and dehydroiodination. The synthetic strategy can also be extended to the cyclization of ortho-methylthiophenyl vinyl ketones leading to 2-methylene-3-benzothiophenones.