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2-Ethoxyethyl acetate

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Name

2-Ethoxyethyl acetate

EINECS 203-839-2
CAS No. 111-15-9 Density 0.961 g/cm3
PSA 35.53000 LogP 0.58600
Solubility 230 g/L (20 °C) in water Melting Point -61 °C
Formula C6H12O3 Boiling Point 156.1 °C at 760 mmHg
Molecular Weight 132.159 Flash Point 50.6 °C
Transport Information UN 1172 3/PG 3 Appearance colourless liquid
Safety 53-45 Risk Codes 60-61-20/21/22-10
Molecular Structure Molecular Structure of 111-15-9 (Ethylene glycol monoethyl ether acetate) Hazard Symbols ToxicT
Synonyms

b-Ethoxyethyl acetate;Ethanol,2-ethoxy-, acetate (6CI,7CI,8CI,9CI);1-Acetoxy-2-ethoxyethane;2-Ethoxyethanolacetate;Ethanol, 2-ethoxy-,1-acetate;Cellosolve acetate;Ethyl cellosolve acetate;Ethylene glycol acetate monoethyl ether;Ethylene glycol ethyl ether acetate;Ethylene glycol monoethyl ether acetate;Ethylene glycol monoethyl ethermonoacetate;Glycol monoethyl ether acetate;Poly-Solv EE acetate;

Article Data 15

2-Ethoxyethyl acetate Synthetic route

110-80-5

2-ethoxy-ethanol

108-05-4

vinyl acetate

111-15-9

2-ethoxyethyl acetate

Conditions
ConditionsYield
With dilithium tetra(tert-butyl)zincate In toluene at 0℃; for 1h; Inert atmosphere;100%
90325-45-4

1-ethoxy-2-methoxymethoxy-ethane

141-78-6

ethyl acetate

111-15-9

2-ethoxyethyl acetate

Conditions
ConditionsYield
With indium (III) iodide for 17h; Heating;82%
110-80-5

2-ethoxy-ethanol

141-78-6

ethyl acetate

111-15-9

2-ethoxyethyl acetate

Conditions
ConditionsYield
With indium; iodine for 14h; Heating;78%
141-78-6

ethyl acetate

2-(2-ethoxy-ethoxy)-tetrahydro-pyran

111-15-9

2-ethoxyethyl acetate

Conditions
ConditionsYield
With indium (III) iodide for 12h; Heating;78%
110-80-5

2-ethoxy-ethanol

546-67-8

lead(IV) tetraacetate

A

497-26-7

2-methyl-1,3-dioxolane

B

111-15-9

2-ethoxyethyl acetate

C

141-78-6

ethyl acetate

Conditions
ConditionsYield
In chlorobenzene at 140℃; for 0.5h;A 27%
B 63%
C 10%
110-80-5

2-ethoxy-ethanol

A

497-26-7

2-methyl-1,3-dioxolane

B

111-15-9

2-ethoxyethyl acetate

C

141-78-6

ethyl acetate

Conditions
ConditionsYield
With lead(IV) acetate In chlorobenzene at 140℃; for 0.5h; glass tube;A 27%
B 63%
C 10%
110-80-5

2-ethoxy-ethanol

463-51-4

Ketene

111-15-9

2-ethoxyethyl acetate

Conditions
ConditionsYield
With sulfuric acid
506-96-7

Acetyl bromide

61911-33-9

benzyl cellosolve

A

74-96-4

ethyl bromide

B

111-15-9

2-ethoxyethyl acetate

C

111-55-7

ethylene glycol diacetate

D

100-39-0

benzyl bromide

Conditions
ConditionsYield
at 92℃;
110-80-5

2-ethoxy-ethanol

108-24-7

acetic anhydride

111-15-9

2-ethoxyethyl acetate

110-80-5

2-ethoxy-ethanol

64-19-7

acetic acid

111-15-9

2-ethoxyethyl acetate

Conditions
ConditionsYield
With toluene-4-sulfonic acid man entfernt das entstehende Wasser durch azeotrope Destillation mit Benzol;

2-Ethoxyethyl acetate Chemical Properties

Molecular Structure of 2-Ethoxyethyl acetate (CAS NO.111-15-9):

IUPAC Name: 2-Ethoxyethyl acetate 
Molecular Weight: 132.15768 g/mol
Molecular Formula: C6H12O3 
Density: 0.961 g/cm3 
Melting Point: -61 °C
Boiling Point: 156.1 °C at 760 mmHg 
Flash Point: 50.6 °C
Index of Refraction: 1.4
Molar Refractivity: 33.36 cm3
Molar Volume: 137.4 cm3
Surface Tension: 27.6 dyne/cm 
Enthalpy of Vaporization: 39.28 kJ/mol
Vapour Pressure: 2.94 mmHg at 25 °C 
Water Solubility: 230 g/L (20 °C)
XLogP3-AA: 0.3
H-Bond Acceptor: 3
Rotatable Bond Count: 5
Exact Mass: 132.078644
MonoIsotopic Mass: 132.078644
Topological Polar Surface Area: 35.5
Heavy Atom Count: 9
Canonical SMILES: CCOCCOC(=O)C
InChI: InChI=1S/C6H12O3/c1-3-8-4-5-9-6(2)7/h3-5H2,1-2H3
InChIKey: SVONRAPFKPVNKG-UHFFFAOYSA-N
EINECS: 203-839-2
Product Categories: Ethylene-Ethyl Acrylate Copolymer

2-Ethoxyethyl acetate Uses

 2-Ethoxyethyl acetate (CAS NO.111-15-9) is used as a solvent dissolve resin, leather, ink.

2-Ethoxyethyl acetate Toxicity Data With Reference

1.    

skn-rbt 490 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/13 ,1967.
2.    

eye-rbt 40 mg MOD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/13 ,1967.
3.    

orl-rat LD50:2900 mg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 51 (1979),117.
4.    

ihl-rat LC50:12,100 mg/m3/8H

    AIHAAP    American Industrial Hygiene Association Journal. 20 (1959),364.
5.    

ipr-mus LD50:1420 mg/kg

    SCCUR*    Shell Chemical Company. Unpublished Report. (2401 Crow Canyon Rd., San Romon, CA 94583)
6.    

orl-rbt LD50:1950 mg/kg

    EPASR*    United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. (U.S. Environmental Protection Agency, 401M St., S.W., Washington, DC 20460) History Unknown 8EHQ-0682-0450 .
7.    

skn-rbt LD50:10,500 mg/kg

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 1/13 ,1967.

2-Ethoxyethyl acetate Consensus Reports

Reported in EPA TSCA Inventory. Glycol ether compounds are on the Community Right-To-Know List.

2-Ethoxyethyl acetate Safety Profile

Hazard Codes: ToxicT
Risk Statements: 60-61-20/21/22-10 
R60:May impair fertility. 
R61:May cause harm to the unborn child. 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed. 
R10:Flammable.
Safety Statements: 53-45 
S53:Avoid exposure - obtain special instructions before use. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 1172 3/PG 3
WGK Germany: 1
RTECS: KK8225000
HazardClass: 3
PackingGroup: III
Moderately toxic by ingestion and intraperitoneal routes. A skin and eye irritant. An experimental teratogen. Other experimental reproductive effects. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. Moderate explosion hazard in the form of vapor when heated. Mild explosions have occurred at the end of distillations. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS.

2-Ethoxyethyl acetate Standards and Recommendations

OSHA PEL: TWA 100 ppm (skin)
ACGIH TLV: TWA 5 ppm (skin); BEI: 100 mg/g creatinine of 2-ethoxyacetic acid in urine end of shift at end of workweek
DFG MAK: 5 ppm (27 mg/m3)
DOT Classification:  3; Label: Flammable Liquid

2-Ethoxyethyl acetate Analytical Methods

For occupational chemical analysis use OSHA: #53 or NIOSH: Esters I, 1450.

2-Ethoxyethyl acetate Specification

 2-Ethoxyethyl acetate (CAS NO.111-15-9) is also named as 1-Acetoxy-2-ethoxyethane ; 2-Aethoxy-aethylacetat ; 2-Aethoxy-aethylacetat [German] ; 2-Ethoxy-ethylacetaat ; 2-Ethoxy-ethylacetaat [Dutch] ; 2-Ethoxyethanol, ester with acetic acid ; 2-Ethoxyethylacetate ; 2-Ethoxyethyle, acetate de ; 2-Ethoxyethyle, acetate de [French] ; 2-Ethoxyethylester kyseliny octove ; 2-Ethoxyethylester kyseliny octove [Czech] ; 2-Etossietil-acetato ; 2-Etossietil-acetato [Italian] ; 4-02-00-00214 (Beilstein Handbook Reference) ; AI3-01955 (USDA) ; Acetate d'ethylglycol ; Acetate d'ethylglycol [French] ; Acetate de cellosolve ; Acetate de cellosolve [French] ; Acetate de l'ether monoethylique de l'ethylene-glycol ; Acetate de l'ether monoethylique de l'ethylene-glycol [French] ; Acetato di cellosolve ; Acetato di cellosolve [Italian] ; Acetic acid, 2-ethoxyethyl ester ; Ethanol, 2-ethoxy-, acetate ; Ethoxyethyl acetate ; Ethyleneglycol monoethyl ether acetate ; HSDB 539 ; NSC 8658 ; Octan etoksyetylu ; Octan etoksyetylu [Polish] ; Oxitol acetate ; Oxytol acetate ; Poly-Solv EE acetate . 2-Ethoxyethyl acetate (CAS NO.111-15-9) is colourless liquid with a pleasant odor. Vapors are heavier than air. It is flammable and slightly soluble in water.Mixing Ethylene glycol monoethyl ether acetate in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid, oleum, and vinyl acetate. Vapors irritate nose and eyes in high concentrations. Liquid irritates skin in prolonged or repeated contact. It will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated.

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