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Benzo(j)fluoranthene

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Name

Benzo(j)fluoranthene

EINECS N/A
CAS No. 205-82-3 Density 1.286g/cm3
PSA 0.00000 LogP 5.64040
Solubility 2.5ug/L(temperature not stated) Melting Point 166°C
Formula C20H12 Boiling Point 467.5°Cat760mmHg
Molecular Weight 252.315 Flash Point 228.6°C
Transport Information N/A Appearance N/A
Safety Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. Risk Codes 45-50/53-63-43-36/37/38-23/24/25
Molecular Structure Molecular Structure of 205-82-3 (BENZO(J)FLUORANTHENE) Hazard Symbols
Synonyms

10,11-Benzofluoranthene;7,8-Benzfluoranthene; Benzo-12,13-fluoranthene; Dibenzo[a,jk]fluorene

Article Data 41

Benzo(j)fluoranthene Synthetic route

146746-41-0

8-hydroxy-1-(1-naphtyl)naphthalene triflate

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; bis(triphenylphosphine)palladium(II)-chloride In N,N-dimethyl-formamide at 140℃; for 10h;93%
18522-48-0

(+/-)-1,2,3,6b,7,8-hexahydrobenzofluoranthene

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
palladium on activated charcoal In various solvent(s) for 5h; Heating;92%
74983-82-7

(+/-)-cis,syn-4,5,6,6a,6b,7,8,12b,octahydrobenzofluoranthene

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
palladium on activated charcoal for 84h; Heating;92%

2-(2-formylphenyl)acenaphthylene-1-carbaldehyde

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With tetrahydrofuran; pyridine; titanium tetrachloride; zinc for 4h; McMurry Reaction; Reflux;83%

7-(methylthio)benzo[j]fluoranthene

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
Raney Ni (W2) In ethanol for 7h; Heating;57%
33084-86-5

azuleno<1,2-a>acenaphthylene

A

207-08-9

Benzo[k]fluoranthene

B

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
In benzene at 600℃;A 14%
B 28%

[1,2′-binaphthalen]-8-yl nonafluorobutanesulfonate

A

207-08-9

Benzo[k]fluoranthene

B

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); 1-Adamantanecarboxylic acid In N,N-dimethyl acetamide at 110℃; for 24h; Inert atmosphere;A 26%
B 8%
56-23-5

tetrachloromethane

128-08-5

N-Bromosuccinimide

19390-93-3, 23672-05-1, 23756-78-7, 74983-82-7

4,5,6,6a,6b,7,8,12b-octahydro-benzo[j]fluoranthene

94-36-0

dibenzoyl peroxide

205-82-3

Benzo[j]fluoranthene

128-08-5

N-Bromosuccinimide

18511-30-3

1,2,3,6b,7,8,12b,12c-octahydro-benzo[j]fluoranthene

94-36-0

dibenzoyl peroxide

205-82-3

Benzo[j]fluoranthene

62393-33-3

benzo[j]fluoranthen-1-ol

205-82-3

Benzo[j]fluoranthene

Conditions
ConditionsYield
With hydrogen; zinc

Benzo(j)fluoranthene Chemical Properties

 Benzo(j)fluoranthene with CAS number of 205-82-3 is called for 10,11-Benzfluoranthene ; 10,11-benzofluoranthene ; 7,8-Benzofluoranthene ; B(j)F ; Benz(j)fluoranthene ; Benzo(l)fluoranthene ; Benzo[l]fluoranthene ; Dibenzo(a,jk)fluorene ,and so on. Benzo(j)fluoranthene is usually yellow crystals.
CAS: 205-82-3
Molecular Formula: C20H12
Molecular Weight: 252.31
Molecular structure:
EINECS: 205-910-3
Storage temp.:  2-8°C
ACD/LogD (pH 5.5): 6.4 
ACD/LogD (pH 7.4): 6.4 
ACD/BCF (pH 5.5): 43177 
ACD/BCF (pH 7.4): 43177 
ACD/KOC (pH 5.5): 72359.67 
ACD/KOC (pH 7.4): 72359.67 
H bond acceptors: 0 
H bond donors: 0 
Freely Rotating Bonds: 0 
Index of Refraction: 1.887 
Molar Refractivity: 90.3 cm3 
Molar Volume: 196 cm3 
Polarizability: 35.8×10-24cm3 
Surface Tension: 63.4 dyne/cm 
Density: 1.286 g/cm3 
Flash Point: 228.6 °C 
Enthalpy of Vaporization: 70.16 kJ/mol 
Boiling Point: 467.5 °C at 760 mmHg 
Vapour Pressure: 1.81E-08 mmHg at 25°C

Benzo(j)fluoranthene Uses

 Benzo(j)fluoranthene (CAS No.205-82-3) is supposed to be used as chemical reagent.

Benzo(j)fluoranthene Toxicity Data With Reference

1.    

mma-sat 10 µg/plate

    CNREA8    Cancer Research. 40 (1980),4258.
2.    

dnd-mus-skn 3760 nmol/kg

    PAACA3    Proceedings of the American Association for Cancer Research. 25 (1984),121.

Benzo(j)fluoranthene Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 2B IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Limited Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 3 (1973),p. 82.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 155.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) .

Benzo(j)fluoranthene Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes.

Hazard Codes:  T,N  
Risk Statements:  45-50/53-63-43-36/37/38-23/24/25 (R45:May cause cancer. R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R63:Possible risk of harm to the unborn child. R43:May cause sensitization by skin contact. R36/37/38:Irritating to eyes, respiratory system and skin. R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.)
Safety Statements:  45-53-61-60-36/37-24/25-23 (S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S53:Avoid exposure - obtain special instructions before use. S61:Avoid release to the environment. Refer to special instructions / safety data sheets. S60:This material and its container must be disposed of as hazardous waste. S36/37:Wear suitable protective clothing and gloves. S24/25:Avoid contact with skin and eyes. S23:Do not breathe vapour.)
RIDADR:  3077
HazardClass:  6.1(b)
PackingGroup:  III

Benzo(j)fluoranthene Specification

Removal in wastewater treatment of Benzo(j)fluoranthene (CAS No.205-82-3) can be stated as follows:
Total removal:90.94  percent
Total biodegradation:0.76  percent
Total sludge adsorption:90.18  percent
Total to Air:0.00  percent
(using 10000 hr Bio P,A,S)

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